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Abstract Stellar abundance measurements are subject to systematic errors that induce extra scatter and artificial correlations in elemental abundance patterns. We derive empirical calibration offsets to remove systematic trends with surface gravity $\log \left(g\right)$in 17 elemental abundances of 288,789 evolved stars from the SDSS APOGEE survey. We fit these corrected abundances as the sum of a prompt process tracing core-collapse supernovae and a delayed process tracing Type Ia supernovae, thus recasting each star’s measurements into the amplitudesA_ccandA_Iaand the element-by-element residuals from this two-parameter fit. As a first application of this catalog, which is 8× larger than that of previous analyses that used a restricted $\log \left(g\right)$range, we examine the median residual abundances of 14 open clusters, nine globular clusters, and four dwarf satellite galaxies. Relative to field Milky Way disk stars, the open clusters younger than 2 Gyr show ≈0.1−0.2 dex enhancements of the neutron-capture element Ce, and the two clusters younger than 0.5 Gyr also show elevated levels of C+N, Na, S, and Cu. Globular clusters show elevated median abundances of C+N, Na, Al, and Ce, and correlated abundance residuals that follow previously known trends. The four dwarf satellites show similar residual abundance patterns despite their different star formation histories, with ≈0.2–0.3 dex depletions in C+N, Na, and Al and ≈0.1 dex depletions in Ni, V, Mn, and Co. We provide our catalog of corrected APOGEE abundances, two-process amplitudes, and residual abundances, which will be valuable for future studies of abundance patterns in different stellar populations and of additional enrichment processes that affect galactic chemical evolution. 

ABSTRACT Standard stellar evolution theory poorly predicts the surface abundances of chemical species in low-mass, red giant branch (RGB) stars. Observations show an enhancement of p–p chain and CNO cycle products in red giant envelopes, which suggests the existence of non-canonical mixing that brings interior burning products to the surface of these stars. The 12C/13C ratio is a highly sensitive abundance metric used to probe this mixing. We investigate extra RGB mixing by examining: (1) how 12C/13C is altered along the RGB, and (2) how 12C/13C changes for stars of varying age and mass. Our sample consists of 43 red giants, spread over 15 open clusters from the Sloan Digital Sky Survey’s APOGEE DR17, that have reliable 12C/13C ratios derived from their APOGEE spectra. We vetted these 12C/13C ratios and compared them as a function of evolution and age/mass to the standard mixing model of stellar evolution, and to a model that includes prescriptions for RGB thermohaline mixing and stellar rotation. We find that the observations deviate from standard mixing models, implying the need for extra mixing. Additionally, some of the abundance patterns depart from the thermohaline model, and it is unclear whether these differences are due to incomplete observations, issues inherent to the model, our assumption of the cause of extra mixing, or any combination of these factors. Nevertheless, the surface abundances across our age/mass range clearly deviate from the standard model, agreeing with the notion of a universal mechanism for RGB extra mixing in low-mass stars.