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Abstract Twice in the Cryogenian Period (720–635 Ma), during the Sturtian and Marinoan glaciations, ice sheets extended to equatorial latitudes for millions of years. These climate extremes have been interpreted to record the Snowball climate state, in which all of Earth’s oceans were covered with ice. During a Snowball Earth, the hydrological cycle would have been curtailed and silicate weathering greatly reduced. In this scenario, deep ocean chemistry should have evolved toward mantle values through hydrothermal exchange at mid-ocean ridges. Specifically, seawater strontium isotopes (87Sr/86Sr) are predicted to exhibit unradiogenic mantle-like values. However, cap carbonates that overlie the Cryogenian glacial deposits have yielded radiogenic 87Sr/86Sr values similar to those of seawater prior to glaciation, inconsistent with the central geochemical prediction of the Snowball Earth hypothesis. Here we report the discovery of 87Sr/86Sr values of 0.7034 in marine carbonate and authigenic barite that rest directly above Sturtian glacial deposits in Dhofar, Oman. These values record either a local unradiogenic source or Snowball Earth deep-water values that have not been previously identified. If it is a global signal, these new data and geochemical modeling support an extreme Snowball Earth scenario with near-complete ice cover and define one of the largest geochemical perturbations to seawater in Earth history. 

Major and trace element abundances, including highly siderophile elements, and 187Os and 182W isotopic compositions were determined for ca. 89 Ma mafic and ultramafic rocks from the islands of Gorgona (Colombia) and Curaçao (Dutch Caribbean). The volcanic systems of both islands were likely associated with a mantle plume that generated the Caribbean Large Igneous Provence. The major and lithophile trace element characteristics of the rocks examined are consistent with the results of prior studies, and indicate derivation from both a chemically highly-depleted mantle component, and an enriched, or less highly-depleted mantle component. Highly siderophile element abundances for these rocks are generally similar to rocks with comparable MgO globally, indicating that the major source components were not substantially enriched or depleted in these elements. Rhenium-Os isotopic systematics of most rocks of both islands indicate derivation from a mantle source with an initial 187Os/188Os ratio between that of the contemporaneous average depleted mid-ocean ridge mantle and bulk silicate Earth. The composition may reflect either an average lower mantle signature, or global-scale Os isotopic heterogeneity in the upper mantle. Some of the basalts, as well as two of the komatiites, are characterized by calculated initial 187Os/188Os ratios 10-15% higher than the chondritic reference. These more radiogenic Os isotopic compositions do not correlate with major or trace element systematics, and indicate a mantle source component that was most likely produced by either sulfide metasomatism or ancient Re/Os fractionation. Tungsten-182 isotopic compositions measured for rocks from both islands are characterized by variable 182W values ranging from modern bulk silicate Earth-like to strongly negative values. The 182W values do not correlate with major/trace element abundances or initial 187Os/188Os compositions. As with some modern ocean island basalt systems, however, the lowest 182W value (-53) measured, for a Gorgona olivine gabbro, corresponds with the highest 3He/4He previously measured from the suite (15.8 R/RA). Given the lack of correlation with other chemical/isotopic compositions, the mantle component characterized by negative 182W and possibly high 3He/4He is most parsimoniously explained to have formed as a result of isotopic equilibration between the mantle and core at the core-mantle boundary.