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ABSTRACT Measuring interstellar magnetic fields is extremely important for understanding their role in different evolutionary stages of interstellar clouds and star formation. However, detecting the weak field is observationally challenging. We present measurements of the Zeeman effect in the 1665 and 1667 MHz (18 cm) lines of the hydroxyl radical (OH) lines towards the dense photodissociation region (PDR) associated with the compact H ii region DR 21 (Main). From the OH 18 cm absorption, observed with the Karl G. Jansky Very Large Array, we find that the line-of-sight magnetic field in this region is ∼0.13 mG. The same transitions in maser emission towards the neighbouring DR 21(OH) and W 75S-FR1 regions also exhibit the Zeeman splitting. Along with the OH data, we use [C ii] 158 μm line and hydrogen radio recombination line data to constrain the physical conditions and the kinematics of the region. We find the OH column density to be ∼3.6 × 1016(Tex/25 K) cm−2, and that the 1665 and 1667 MHz absorption lines are originating from the gas where OH and C+ are co-existing in the PDR. Under reasonable assumptions, we find the measured magnetic field strength for the PDR to be lower than the value expected from the commonly discussed density–magnetic field relation while the field strength values estimated from the maser emission are roughly consistent with the same. Finally, we compare the magnetic field energy density with the overall energetics of DR 21’s PDR and find that, in its current evolutionary stage, the magnetic field is not dynamically important.