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A bstract Searches for new low-mass matter and mediator particles have actively been pursued at fixed target experiments and at e + e − colliders. It is challenging at the CERN LHC, but they have been searched for in Higgs boson decays and in B meson decays by the ATLAS and CMS Collaborations, as well as in a low transverse momentum phenomena from forward scattering processes (e.g., FASER). We propose a search for a new scalar particle in association with a heavy vector-like quark. We consider the scenario in which the top quark ( t ) couples to a light scalar ϕ′ and a heavy vector-like top quark T . We examine single and pair production of T in pp collisions, resulting in a final state with a top quark that decays purely hadronically, a T which decays semileptonically ( T → W + b → ℓ ν b ), and a ϕ′ that is very boosted and decays to a pair of collimated photons which can be identified as a merged photon system. The proposed search is expected to achieve a discovery reach with signal significance greater than 5 σ (3 σ ) for m ( T ) as large as 1.8 (2) TeV and m ( ϕ′ ) as small as 1 MeV, assuming an integrated luminosity of 3000 fb − 1 . This search can expand the reach of T , and demonstrates that the LHC can probe low-mass, MeV-scale particles.