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Many correlations exist between spectral reflectance or transmission with various phenotypic responses from plants. Of interest to us are metabolic characteristics, namely, how the various polarimetric components of plants may correlate to underlying environmental, metabolic, and genotypic differences among different varieties within a given species, as conducted during large field experimental trials. In this paper, we overview a portable Mueller matrix imaging spectropolarimeter, optimized for field use, by combining a temporal and spatial modulation scheme. Key aspects of the design include minimizing the measurement time while maximizing the signal-to-noise ratio by mitigating systematic error. This was achieved while maintaining an imaging capability across multiple measurement wavelengths, spanning the blue to near-infrared spectral region (405–730 nm). To this end, we present our optimization procedure, simulations, and calibration methods. Validation results, which were taken in redundant and non-redundant measurement configurations, indicated that the polarimeter provides average absolute errors of (5.3±2.2)×10⁻³and (7.1±3.1)×10⁻³, respectively. Finally, we provide preliminary field data (depolarization, retardance, and diattenuation) to establish baselines of barren and non-barrenZea maizehybrids (G90 variety), as captured from various leaf and canopy positions during our summer 2022 field experiments. Results indicate that subtle variations in retardance and diattenuation versus leaf canopy position may be present before they are clearly visible in the spectral transmission. 

Simultaneous spectral and polarimetric imaging enables versatile detection and multimodal characterization of targets of interest. Current architectures incorporate a 2×2 pixel arrangement to acquire the full linear polarimetric information causing spatial sampling artifacts. Additionally, they suffer from limited spectral selectivity and high color crosstalk. Here, we demonstrate a bio-inspired spectral and polarization sensor structure based on integrating semitransparent polarization-sensitive organic photovoltaics (P-OPVs) and liquid crystal polymer (LCP) retarders in a tandem configuration. Color tuning is realized by leveraging the dynamic chromatic retardation control of LCP films, while polarization sensitivity is realized by exploiting the flexible anisotropic properties of P-OPVs. The structure is marked by its ultra-thin design and its ability to detect spectral and polarimetric contents along the same optical axis, thereby overcoming the inherent limitations associated with conventional division-of-focal plane sensors. 

Channeled spectropolarimetry measures the spectral dependence of the polarization states of light. This technique is marked by its snapshot feature, in that the complete polarization states can be determined simultaneously from a single intensity spectrum. However, without athermalization, it suffers from high sensitivity to temperature, which in turn, degrades the polarimetric reconstruction accuracy. In this paper, we present a calibration technique for a fiber-based channeled spectropolarimetry that leverages phase-shifting interferometry to accurately demodulate the retarders' phase, thereby improving the accuracy of the acquired Stokes parameters. Additionally, it enables robust spectropolarimetric performance that is insensitive to environmental perturbations. Experimental results demonstrate that calibrations using phase-shifting interferometry improve the Stokes reconstruction results by approximately a factor of 3 when compared to the reference beam calibration method. 

Combining hyperspectral and polarimetric imaging provides a powerful sensing modality with broad applications from astronomy to biology. Existing methods rely on temporal data acquisition or snapshot imaging of spatially separated detectors. These approaches incur fundamental artifacts that degrade imaging performance. To overcome these limitations, we present a stomatopod-inspired sensor capable of snapshot hyperspectral and polarization sensing in a single pixel. The design consists of stacking polarization-sensitive organic photovoltaics (P-OPVs) and polymer retarders. Multiple spectral and polarization channels are obtained by exploiting the P-OPVs’ anisotropic response and the retarders’ dispersion. We show that the design can sense 15 spectral channels over a 350-nanometer bandwidth. A detector is also experimentally demonstrated, which simultaneously registers four spectral channels and three polarization channels. The sensor showcases the myriad degrees of freedom offered by organic semiconductors that are not available in inorganics and heralds a fundamentally unexplored route for simultaneous spectral and polarimetric imaging.