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Conjugated microporous polymers (CMPs) are an emerging class of porous organic polymers that combine -conjugated skeletons with permanent micropores. Since their first report in 2007, the enormous exploration of linkage types, building units, and synthetic methods for CMPs have facilitated their potential applications in various areas, from gas separations to energy storage. Owning to their unique construction, CMPs offer the opportunity for the precise design of conjugated skeletons and pore environment engineering, which allow the construction of functional porous materials at the molecular level. The capability to chemically alter CMPs to targeted applications allows for the fine adaptation of functionalities for the ever changing environments and necessities. Bifunctional CMPs are a branch of functionalized CMPs that have caught interest of researchers because of their inherent synergistic systems that can expand their applications and optimize their performance. This review attempts to discuss the rational design and synthesis for bifunctional CMPs and summarize their advanced applications. To conclude, our own perspective on the research prospect of this type of material is outlined. 

Abstract Titanium metal–organic frameworks (Ti‐MOFs), as an appealing type of artificial photocatalyst, have shown great potential in the field of solar energy conversion due to their well‐studied photoredox activity (similar to TiO₂) and good optical responsiveness of linkers, which serve as the antenna to absorb visible‐light. Although much effort has been dedicated to developing Ti‐MOFs with high photocatalytic activity, their solar energy conversion performances are still poor. Herein, we have implemented a covalent‐integration strategy to construct a series of multivariate Ti‐MOF/COF hybrid materials PdTCPP⊂PCN‐415(NH₂)/TpPa (composites 1, 2, and 3), featuring excellent visible‐light utilization, a suitable band gap, and high surface area for photocatalytic H₂production. Notably, the resulting composites demonstrated remarkably enhanced visible‐light‐driven photocatalytic H₂evolution performance, especially for the composite 2 with a maximum H₂evolution rate of 13.98 mmol g⁻¹ h⁻¹(turnover frequency (TOF)=227 h⁻¹), which is much higher than that of PdTCPP⊂PCN‐415(NH₂) (0.21 mmol g⁻¹ h⁻¹) and TpPa (6.51 mmol g⁻¹ h⁻¹). Our work thereby suggests a new approach to highly efficient photocatalysts for H₂evolution and beyond.