skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Search for: All records

Creators/Authors contains: "Larsen, Kirk"

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. Resources for passive acoustic monitoring (PAM) are continuously expanding and being developed, yet a major challenge for users is staying up-to-date and finding the best software or application for their acoustics investigation. We expand on previous efforts (Rhinehart & Nicholson, 2022; Felgate, 2023) with the aim of providing a current, comprehensive list of 1) underwater sound repositories of raw sound data without significant processing, 2) biological sound reference libraries, with species or taxa identification, and 3) sound processing tools for visualization, annotation, or analysis. This spreadsheet contains three pages, one dedicated to each of the aforementioned items, along with some descriptive information to help users identify the best resources for their needs. This work was done to support the Global Library of Underwater Biological Sounds (GLUBS) project and funded in part by the Richard Lounsbery Foundation and from funding to SCOR WG #169 (GLUBS) provided by national committees of the Scientific Committee on Oceanic Research (SCOR) and from a grant to SCOR from the US National Science Foundation (OCE--2140395), with support from the International Quiet Ocean Experiment.   
    more » « less
  2. Abstract Advances in x-ray free electron lasers have made ultrafast scattering a powerful method for investigating molecular reaction kinetics and dynamics. Accurate measurement of the ground-state, static scattering signals of the reacting molecules is pivotal for these pump-probe x-ray scattering experiments as they are the cornerstone for interpreting the observed structural dynamics. This article presents a data calibration procedure, designed for gas-phase x-ray scattering experiments conducted at the Linac Coherent Light Source x-ray Free-Electron Laser at SLAC National Accelerator Laboratory, that makes it possible to derive a quantitative dependence of the scattering signal on the scattering vector. A self-calibration algorithm that optimizes the detector position without reference to a computed pattern is introduced. Angle-of-scattering corrections that account for several small experimental non-idealities are reported. Their implementation leads to near quantitative agreement with theoretical scattering patterns calculated withab-initiomethods as illustrated for two x-ray photon energies and several molecular test systems. 
    more » « less
  3. Abstract The double photoionization of a molecule by one photon ejects two electrons and typically creates an unstable dication. Observing the subsequent fragmentation products in coincidence can reveal a surprisingly detailed picture of the dynamics. Determining the time evolution and quantum mechanical states involved leads to deeper understanding of molecular dynamics. Here in a combined experimental and theoretical study, we unambiguously separate the sequential breakup via D +  + OD + intermediates, from other processes leading to the same D +  + D +  + O final products of double ionization of water by a single photon. Moreover, we experimentally identify, separate, and follow step by step, two pathways involving the b  1 Σ + and a 1 Δ electronic states of the intermediate OD + ion. Our classical trajectory calculations on the relevant potential energy surfaces reproduce well the measured data and, combined with the experiment, enable the determination of the internal energy and angular momentum distribution of the OD + intermediate. 
    more » « less
  4. Abstract We present state-selective measurements on the N H 2 + + H + and NH + + H + + H dissociation channels following single-photon double ionization at 61.5 eV of neutral NH 3 , where the two photoelectrons and two cations are measured in coincidence using 3D momentum imaging. Three dication electronic states are identified to contribute to the N H 2 + + H + dissociation channel, where the excitation in one of the three states undergoes intersystem crossing prior to dissociation, producing a cold N H 2 + fragment. In contrast, the other two states directly dissociate, producing a ro-vibrationally excited N H 2 + fragment with roughly 1 eV of internal energy. The NH + + H + + H channel is fed by direct dissociation from three intermediate dication states, one of which is shared with the N H 2 + + H + channel. We find evidence of autoionization contributing to each of the double ionization channels. The distributions of the relative emission angle between the two photoelectrons, as well as the relative angle between the recoil axis of the molecular breakup and the polarization vector of the ionizing field, are also presented to provide insight on both the photoionization and photodissociation mechanisms for the different dication states. 
    more » « less
  5. Abstract Climate change models often assume similar responses to temperatures across the range of a species, but local adaptation or phenotypic plasticity can lead plants and animals to respond differently to temperature in different parts of their range. To date, there have been few tests of this assumption at the scale of continents, so it is unclear if this is a large‐scale problem. Here, we examined the assumption that insect taxa show similar responses to temperature at 96 sites in grassy habitats across North America. We sampled insects with Malaise traps during 2019–2021 (N = 1041 samples) and examined the biomass of insects in relation to temperature and time of season. Our samples mostly contained Diptera (33%), Lepidoptera (19%), Hymenoptera (18%), and Coleoptera (10%). We found strong regional differences in the phenology of insects and their response to temperature, even within the same taxonomic group, habitat type, and time of season. For example, the biomass of nematoceran flies increased across the season in the central part of the continent, but it only showed a small increase in the Northeast and a seasonal decline in the Southeast and West. At a smaller scale, insect biomass at different traps operating on the same days was correlated up to ~75 km apart. Large‐scale geographic and phenological variation in insect biomass and abundance has not been studied well, and it is a major source of controversy in previous analyses of insect declines that have aggregated studies from different locations and time periods. Our study illustrates that large‐scale predictions about changes in insect populations, and their causes, will need to incorporate regional and taxonomic differences in the response to temperature. 
    more » « less