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In recent years, global efforts towards a future with sustainable energy have intensified the development of renewable energy sources (RESs) such as offshore wind, solar photovoltaics (PVs), hydro, and geothermal. Concurrently, green hydrogen, produced via water electrolysis using these RESs, has been recognized as a promising solution to decarbonizing traditionally hard-to-abate sectors. Furthermore, hydrogen storage provides a long-duration energy storage approach to managing the intermittency of RESs, which ensures a reliable and stable electricity supply and supports electric grid operations with ancillary services like frequency and voltage regulation. Despite significant progress, the hydrogen economy remains nascent, with ongoing developments and persistent uncertainties in economic, technological, and regulatory aspects. This paper provides a comprehensive review of the green hydrogen value chain, encompassing production, transportation logistics, storage methodologies, and end-use applications, while identifying key research gaps. Particular emphasis is placed on the integration of green hydrogen into both grid-connected and islanded systems, with a focus on operational strategies to enhance grid resilience and efficiency over both the long and short terms. Moreover, this paper draws on global case studies from pioneering green hydrogen projects to inform strategies that can accelerate the adoption and large-scale deployment of green hydrogen technologies across diverse sectors and geographies.

 

Incorporation of ferric iron in mantle silicates stabilizes different crystal structures and changes phase transition conditions, thus impacting seismic wave speeds and discontinuities. In MgSiO3-Fe2O3 mixtures, recent experiments indicate the coexistence of fully oxidized iron-rich (Mg0.5Fe0.53+)(Fe0.53+Si0.5)O3 with Fe-poor silicate (wadsleyite or bridgmanite) and stishovite at 15 to 27 GPa and 1773 to 2000 K, conditions relevant to subducted lithosphere in the Earth’s transition zone and uppermost lower mantle. X-ray diffraction measurements show that (Mg0.5Fe0.53+)(Fe0.53+Si0.5)O3 recovered from these conditions adopts the R3c LiNbO3-type structure, which transforms to the bridgmanite structure again between 18.3 GPa and 24.7 GPa at 300 K. Diffraction observations are used to obtain the equation of state of the LiNbO3-type phase up to 18.3 GPa. These observations combined with multi-anvil experiments suggest that the stable phase of (Mg0.5Fe0.53+)(Fe0.53+Si0.5)O3 is bridgmanite at 15-27 GPa, which transforms on decompression to LiNbO3-type structure. Our calculation revealed that ordering of the ferric ion reduces the kinetic energy barrier of the transition between (Mg0.5Fe0.53+)(Fe0.53+Si0.5)O3 LiNbO3 structure and bridgmanite relative to the MgSiO3 akimotoite-bridgmanite system. Dense Fe3+-rich bridgmanite structure is thus stable at substantially shallower depths than MgSiO3 bridgmanite and would promote subduction.

 

Suture zones located across the Tibetan region clearly demarcate the rift-and-drift and continental accretion history of the region. However, the intraplate responses to these marginal plate-tectonic events are rarely quantified. Our understanding of the Paleo-Tethyan orogenic system, which involved ocean opening and closing events to grow the central Asian continent, depends on the tectonic architecture and histories of major late Paleozoic−early Mesozoic orogenic belts. These opening and collision events were associated with coupled intracontinental deformation, which has been difficult to resolve due to subsequent overprinting deformation. The late Paleozoic−early Mesozoic Zongwulong Shan−Qinghai Nanshan belt in northern Tibet separates the Qilian and North Qaidam regions and is composed of Carboniferous−Triassic sedimentary materials and mantle-derived magmatic rocks. The tectonic setting and evolutional history of this belt provide important insight into the paleogeographic and tectonic relationships of the Paleo-Tethyan orogenic system located ∼200 km to the south. In this study, we integrated new and previous geological observations, detailed structural mapping, and zircon U-Pb geochronology data from the Zongwulong Shan−Qinghai Nanshan to document a complete tectonic inversion cycle from intraplate rifting to intracontinental shortening associated with the opening and closing of the Paleo-Tethyan Ocean. Carboniferous−Permian strata in the Zongwulong Shan were deposited in an intracontinental rift basin and sourced from both the north and the south. At the end of the Early−Middle Triassic, foreland molasse strata were deposited in the southern part of the Zongwulong Shan during tectonic inversion in the western part of the tectonic belt following the onset of regional contraction deformation. The Zongwulong Shan−Qinghai Nanshan system has experienced polyphase deformation since the late Paleozoic, including: (1) early Carboniferous intracontinental extension and (2) Early−Middle Triassic tectonic inversion involving reactivation of older normal faults as thrusts and folding of pre- and synrift strata. We interpret that the Zongwulong Shan−Qinghai Nanshan initiated as a Carboniferous−Early Triassic intracontinental rift basin related to the opening of the Paleo-Tethyan Ocean to the south, and it was then inverted during the Early−Middle Triassic closing of the Paleo-Tethyan Ocean. This work emphasizes that pre-Cenozoic intraplate structures related to the opening and closing of ocean basins in the Tethyan realm may be underappreciated across Tibet. 

Recent studies have demonstrated the superiority of cell-to-cell transmission over cell-free virus infection, and highlighted the role of inflammatory cytokines in enhancing viral infection. To investigate their impacts on viral infection dynamics, we have proposed an HIV infection model incorporating general incidence rates, these infection modes, and two time delays. We derived the basic reproduction number and showed that it governs the existence and local stability of steady states. Through the construction of appropriate Lyapunov functionals and application of the LaSalle invariance principle, we established the global asymptotic stability of both the infection-free and infected steady states.

 

The construction of Earth’s largest highland, the Tibetan Plateau, is generally considered to have been generated by the Cenozoic India-Asia collision. However, the extent to which high topography existed prior to the Cenozoic remains unclear. The Hexi Corridor foreland basin of the northern Tibetan Plateau is an ideal region in which to investigate this history, given its widespread exposure of Early Cretaceous sedimentary sequences. In this study, we examined the Early Cretaceous strata in the northern Hexi Corridor to understand the relationships between pre-Cenozoic sedimentation and tectonic deformation and constrain the late Mesozoic tectonic setting of the adjacent Qilian Shan and Alxa blocks bordering the northern Tibetan Plateau. Results of sandstone petrology analyses, paleocurrent observations, and U-Pb geochronology suggest that the oldest Early Cretaceous sediments deposited in the northern Hexi Corridor were sourced from the southern Alxa block during the earliest Cretaceous. By the late Early Cretaceous, Hexi Corridor sediments were sourced from both the southern Alxa block to the north and the Qilian Shan to the south. Sandstone petrologic results indicate that the northern Hexi Corridor experienced a tectonic transition from contraction to extension during the Early Cretaceous. These findings suggest that the northern Tibetan Plateau region was partially uplifted to a high elevation during the late Mesozoic before the India-Asia collision. 

The first highly regioselective tandem indole formation/Truce–Smiles rearrangement controlled by choice of ligands for K+is presented. Use of N,N-diethylethylenediamine gives 2,3-disubstituted indoles whereas 18-crown-6 gives benzhydryl indoles.