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Ring-Opening Metathesis Polymerization of the Dewar Isomer of 1,2-Azaborinine, a B–N Isostere of Benzene

https://doi.org/10.1021/acsmacrolett.3c00601

Lin, Huina; Yang, Xinyu; Liu, Shih-Yuan; Jäkle, Frieder (December 2023, ACS Macro Letters)

The successful polymerization of the Dewar isomer of an azaborinine heterocycle is reported. Controlled ring-opening metathesis polymerization was accomplished with Grubbs and Hoveya−Grubbs second generation catalysts (G2, HG2), as well as a Z-selective Ru catalyst (HGM2001). The structure of the polymers containing 4-membered B−N heterocycles was verified by GPC and multinuclear and 2D NMR. Differences in stereochemistry of polymers derived from G2/HG2 versus the Z-selective catalyst HGM2001 were substantiated by 2D NOESY, FT-IR, and Raman analyses. The incorporation of B−N heterocycles into these polymer structures is promising as a route to functional polymers that contain polar side groups.
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Theoretical Examination of the Hydroxide Transport in Cobaltocenium-Containing Polyelectrolytes

https://doi.org/10.1021/acs.jpcb.3c04118

Wickramasinghe, Sachith; Hoehn, Alexandria; Wetthasinghe, Shehani T; Lin, Huina; Wang, Qi; Jakowski, Jacek; Rassolov, Vitaly; Tang, Chuanbing; Garashchuk, Sophya (November 2023, The Journal of Physical Chemistry B)

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Synthesis of cationic cobaltocenophane monomers: Isomerization and ring-opening metathesis polymerization

https://doi.org/10.1016/j.polymer.2022.124544

Cha, Yujin; Hwang, JiHyeon; Ramos, Luis; Lin, Huina; Zhu, Tianyu; Tang, Chuanbing (March 2022, Polymer)

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Stability Analysis of Substituted Cobaltocenium [Bis(cyclopentadienyl)cobalt(III)] Employing Chemistry-Informed Neural Networks

https://doi.org/10.1021/acs.jctc.1c01201

Li, Chunyan; Wetthasinghe, Shehani T.; Lin, Huina; Zhu, Tianyu; Tang, Chuanbing; Rassolov, Vitaly; Wang, Qi; Garashchuk, Sophya (May 2022, Journal of Chemical Theory and Computation)

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Correlation between the Stability of Substituted Cobaltocenium and Molecular Descriptors

https://doi.org/10.1021/acs.jpca.1c10603

Wetthasinghe, Shehani T.; Li, Chunyan; Lin, Huina; Zhu, Tianyu; Tang, Chuanbing; Rassolov, Vitaly; Wang, Qi; Garashchuk, Sophya (January 2022, The Journal of Physical Chemistry A)

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Tailored Triarylborane Polymers as Supported Catalysts and Luminescent Materials

https://doi.org/10.1021/acs.macromol.0c02258

Lin, Huina; Patel, Shivani; Jäkle, Frieder (December 2020, Macromolecules)
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Mechanochemistry of Cationic Cobaltocenium Mechanophore

https://doi.org/10.1021/jacs.1c05233

Cha, Yujin; Zhu, Tianyu; Sha, Ye; Lin, Huina; Hwang, JiHyeon; Seraydarian, Matthew; Craig, Stephen L.; Tang, Chuanbing (August 2021, Journal of the American Chemical Society)

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Polysiloxane/Polystyrene Thermo-Responsive and Self-Healing Polymer Network via Lewis Acid-Lewis Base Pair Formation

https://doi.org/10.3390/molecules23020405

Vidal, Fernando; Lin, Huina; Morales, Cecilia; Jäkle, Frieder (February 2018, Molecules)

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