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The development of low-cost, highly efficient and stable electrocatalysts for the oxygen evolution reaction (OER) is of great significance for many promising energy storage and conversion applications, including metal–air batteries and water splitting technology. Here we report a layer-structured Ca 0.5 CoO 2 nanofibers composed of interconnected ultrathin nanoplates, synthesized using an electrospinning process. The OER activity of Ca 0.5 CoO 2 can be dramatically improved by iron doping, and the overpotential of Ca 0.5 Co 1− x Fe x O 2 ( x = 0.25) is only 346 mV at a current density of 10 mA cm −2 .more »Free, publicly-accessible full text available March 1, 2023
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Free, publicly-accessible full text available November 1, 2022
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The development of anode materials with high-rate capability is critical to high-power lithium batteries. T-Nb 2 O 5 has been widely reported to exhibit pseudocapacitive behavior and fast lithium storage capability. However, the other polymorphs of Nb 2 O 5 prepared at higher temperatures have the potential to achieve even higher specific capacity and tap density than T-Nb 2 O 5 , offering higher volumetric power and energy density. Here, micrometer-sized H-Nb 2 O 5 with rich Wadsley planar defects (denoted as d-H-Nb 2 O 5 ) is designed for fast lithium storage. The performance of H-Nb 2 O 5more »Free, publicly-accessible full text available January 19, 2023
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Both electronic and ionic conductivities are of high importance to the performance of anode materials for Li-ion batteries. Many large capacity anode materials (such as Ge) do not have sufficiently high electronic and ionic conductivities required for high-rate cycling. Here, we report a novel ternary compound, copper germanium phosphide (CuGe 2 P 3 ), as a high-rate anode. Being synthesized via a facile and scalable mechanochemistry method, CuGe 2 P 3 has a cation-disordered sphalerite structure and offers higher ionic and electronic conductivities and better tolerance to volume change during cycling than Ge, as confirmed by first principles calculations andmore »
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Highly efficient air electrodes are a key component of reversible fuel cells for energy storage and conversion; however, the development of efficient electrodes that are stable against water vapor remains a grand challenge. Here we report an air–electrode, composed of double perovskite material PrBa 0.8 Ca 0.2 Co 2 O 5+δ (PBCC) backbone coated with nanoparticles (NPs) of BaCoO 3−δ (BCO), that exhibits remarkable electrocatalytic activity for oxygen reduction reaction (ORR) while maintaining excellent tolerance to water vapor. When tested in a symmetrical cell exposed to wet air with 3 vol% H 2 O at 750 °C, the electrode showsmore »