Search for: All records

A single-step method for aniline formation was examined. Using a vanadate catalyst with an iron oxide co-catalyst and hydroxylamine hydrochloride as the amine source, an up to 90% yield of aniline was obtained with high selectivity. Further study showed that the overall reaction was pseudo-second order in terms of hydroxylamine concentration. Regioselective H-D exchange experiments suggest that the C-N bond formation step occurs via an irreversible electrophilic pathway. Based on all of the key observations, a mechanism is proposed. 

The Long Wavelength Array is a radio telescope array located at the Sevilleta National Wildlife Refuge in La Joya, New Mexico, well suited and situated for the observation of lightning. The array consists of 256 high-sensitivity dual polarization antennas arranged in a 100 m diameter. This paper demonstrates some of the capabilities that the array brings to the study of lightning. Once 32 or more antennas are used to image lightning radio sources, virtually every integration period longer than the impulse response of the array includes at least one identifiable lightning emitter, independent of the integration period used. The use of many antennas also allows multiple simultaneous lightning radio sources to be imaged at sub-microsecond timescales; for the flash examined, 51% of the images contained more than one lightning source. Finally, by using many antennas to image lightning sources, the array is capable of locating sources fainter than the galactic background radio noise level, yielding possibly the most sensitive radio maps of lightning to date. This incredible sensitivity enables, for the first time, the emissions originating from the positive leader tips of natural in-cloud lightning to be detected and located. The tip emission is distinctly different from needle emission and is most likely due to positive breakdown.

 

Three-dimensional radio and optical mapping reveals that streamers of jets can extend from cloud top to the ionosphere. 

We propose that the upcoming Decadal Survey on Solar and Space Physics describe prominent contributions of lightning and its impacts beyond the troposphere, particularly within the NASA Heliophysics portfolio. We present a brief review of several topics highly relevant to NSF and NASA. We opt to unify these topics into one white paper, with longer reviews/references included. 

Electric fields associated with a developing natural lightning leader are difficult to measure. This work demonstrates a new approach to indirectly probing the electric fields in the streamer zone of a lightning leader. Using a 10–250 MHz broadband lightning interferometer, very high frequency (VHF) radio emissions from the tip of a positive cloud‐to‐ground (CG) leader were measured and localized. We specially use a normalized spectral analysis to avoid the challenge of absolute system calibration to show that the positive leader spectrum exhibits a clear cutoff frequency at 80 MHz. Compared with theoretical predictions, this cutoff frequency corresponds to a streamer growth rate ofand an average electric field of 0.9 times the conventional breakdown fieldin streamer bursts from the positive leader. Implications for the detectability of positive leaders through VHF emissions and for the production of X‐rays by positive leaders are analyzed.

 

Brief bursts of high‐frequency (HF) and very high frequency (VHF) radio emissions unaccompanied by strong low‐frequency radiation have been observed during initiation and propagation of lightning or thunderstorm electrical breakdown without leading to fully fledged lightning. This paper investigates a physical mechanism to generate such radio bursts by electrical discharge activity inside a thundercloud. When a discharge consists of many high‐frequency emission sources, such as streamers, that generate currents in random directions, its radiation spectrum peaks in the HF and VHF bands, and the spectral magnitudes in low frequencies are much smaller or even negligible. Combined with recent observational findings, the present study suggests that lightning initiation may begin with a short burst of many randomly occurring small‐scale discharges in a localized thundercloud region.