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            Abstract We present COSBO-7, a strong millimeter source known for more than 16 yr that just revealed its near-to-mid-IR counterpart with the James Webb Space Telescope (JWST). The precise pinpointing by the Atacama Large Millimeter/submillimeter Array on the exquisite NIRCam and MIRI images show that it is a background source gravitationally lensed by a single foreground galaxy, and the analysis of its spectral energy distribution by different tools is in favor of photometric redshift atzph> 7. Strikingly, our lens modeling based on the JWST data shows that it has a regular disk morphology in the source plane. The dusty region giving rise to the far-IR-to-millimeter emission seems to be confined to a limited region to one side of the disk and has a high dust temperature of >90 K. The galaxy is experiencing starburst both within and outside of this dusty region. After taking the lensing magnification ofμ≈ 2.5–3.6 into account, the intrinsic star formation rate is several hundredM⊙yr−1both within the dusty region and across the more extended stellar disk, and the latter already has >1010M⊙of stars in place. If it is indeed atz> 7, COSBO-7 presents an extraordinary case that is against the common wisdom about galaxy formation in the early Universe; simply put, its existence poses a critical question to be answered: how could a massive disk galaxy come into being so early in the Universe and sustain its regular morphology in the middle of an enormous starburst?more » « less
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            Abstract New JWST/NIRCam wide-field slitless spectroscopy provides redshifts for fourz> 8 galaxies located behind the lensing cluster MACS J0416.1−2403. Two of them, “Y1” and “JD,” have previously reported spectroscopic redshifts based on Atacama Large Millimeter/submillimeter Array measurements of [Oiii] 88μm and/or [Cii] 157.7μm lines. Y1 is a merging system of three components, and the existing redshiftz= 8.31 is confirmed. However, JD is atz= 8.34 instead of the previously claimedz= 9.28. JD’s close companion, “JD-N,” which was a previously discoveredz> 8 candidate, is now identified at the same redshift as JD. JD and JD-N form an interacting pair. A new candidate atz> 8, “f090d_018,” is also confirmed and is atz= 8.49. These four objects are likely part of an overdensity that signposts a large structure extending ∼165 kpc in projected distance and ∼48.7 Mpc in radial distance. They are magnified by less than 1 mag and have an intrinsicMUVranging from −19.57 to −20.83 mag. Their spectral energy distributions show that the galaxies are all very young with ages ∼ 4–18 Myr and stellar masses of about 107–8M⊙. These infant galaxies have very different star formation rates ranging from a few to over a hundred solar masses per year, but only two of them (JD and f090d_018) have blue rest-frame UV slopesβ< −2.0 indicative of a high Lyman-continuum photon escape fraction that could contribute significantly to the cosmic hydrogen-reionizing background. Interestingly, these two galaxies are the least massive and least active ones among the four. The other two systems have much flatter UV slopes largely because of their high dust extinction (AV= 0.9–1.0 mag). Their much lower indicated escape fractions show that even very young, actively star-forming galaxies can have a negligible contribution to reionization when they quickly form dust throughout their bodies.more » « less
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            Abstract The Prime Extragalactic Areas for Reionization and Lensing Science, a James Webb Space Telescope (JWST) GTO program, obtained a set of unique NIRCam observations that have enabled us to significantly improve the default photometric calibration across both NIRCam modules. The observations consisted of three epochs of 4-band (F150W, F200W, F356W, and F444W) NIRCam imaging in the Spitzer IRAC Dark Field (IDF). The three epochs were six months apart and spanned the full duration of Cycle 1. As the IDF is in the JWST continuous viewing zone, we were able to design the observations such that the two modules of NIRCam, modules A and B, were flipped by 180° and completely overlapped each other’s footprints in alternate epochs. We were therefore able to directly compare the photometry of the same objects observed with different modules and detectors, and we found significant photometric residuals up to ∼0.05 mag in some detectors and filters, for the default version of the calibration files that we used (jwst_1039.pmap). Moreover, there are multiplicative gradients present in the data obtained in the two long-wavelength bands. The problem is less severe in the data reduced using the latest pmap (jwst_1130.pmapas of 2023 September), but it is still present, and is non-negligible. We provide a recipe to correct for this systematic effect to bring the two modules onto a more consistent calibration, to a photometric precision better than ∼0.02 mag.more » « less
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            Abstract A new concentrated ternary salt ether‐based electrolyte enables stable cycling of lithium metal battery (LMB) cells with high‐mass‐loading (13.8 mg cm−2, 2.5 mAh cm−2) NMC622 (LiNi0.6Co0.2Mn0.2O2) cathodes and 50 μm Li anodes. Termed “CETHER‐3,” this electrolyte is based on LiTFSI, LiDFOB, and LiBF4with 5 vol% fluorinated ethylene carbonate in 1,2‐dimethoxyethane. Commercial carbonate and state‐of‐the‐art binary salt ether electrolytes were also tested as baselines. With CETHER‐3, the electrochemical performance of the full‐cell battery is among the most favorably reported in terms of high‐voltage cycling stability. For example, LiNixMnyCo1–x–yO2(NMC)‐Li metal cells retain 80% capacity at 430 cycles with a 4.4 V cut‐off and 83% capacity at 100 cycles with a 4.5 V cut‐off (charge at C/5, discharge at C/2). According to simulation by density functional theory and molecular dynamics, this favorable performance is an outcome of enhanced coordination between Li+and the solvent/salt molecules. Combining advanced microscopy (high‐resolution transmission electron microscopy, scanning electron microscopy) and surface science (X‐ray photoelectron spectroscopy, time‐of‐fight secondary ion mass spectroscopy, Fourier‐transform infrared spectroscopy, Raman spectroscopy), it is demonstrated that a thinner and more stable cathode electrolyte interphase (CEI) and solid electrolyte interphase (SEI) are formed. The CEI is rich in lithium sulfide (Li2SO3), while the SEI is rich in Li3N and LiF. During cycling, the CEI/SEI suppresses both the deleterious transformation of the cathode R‐3m layered near‐surface structure into disordered rock salt and the growth of lithium metal dendrites.more » « less
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            Abstract With its unprecedented sensitivity and spatial resolution, the James Webb Space Telescope (JWST) has opened a new window for time-domain discoveries in the infrared. Here we report observations in the only field that has received four epochs (spanning 126 days) of JWST NIRCam observations in Cycle 1. This field is toward MACS J0416.1−2403, which is a rich galaxy cluster at redshiftz= 0.4 and is one of the Hubble Frontier Fields. We have discovered 14 transients from these data. Twelve of these transients happened in three galaxies (withz= 0.94, 1.01, and 2.091) crossing a lensing caustic of the cluster, and these transients are highly magnified by gravitational lensing. These 12 transients are likely of a similar nature to those previously reported based on the Hubble Space Telescope (HST) data in this field, i.e., individual stars in the highly magnified arcs. However, these 12 could not have been found by HST because they were too red and too faint. The other two transients are associated with background galaxies (z= 2.205 and 0.7093) that are only moderately magnified, and they are likely supernovae. They indicate a demagnified supernova surface density, when monitored at a time cadence of a few months to a ∼3–4μm survey limit of AB ∼28.5 mag, of ∼0.5 arcmin−2integrated toz≈ 2. This survey depth is beyond the capability of HST but can be easily reached by JWST.more » « less
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            Abstract Using the first epoch of four-band NIRCam observations obtained by the James Webb Space Telescope (JWST) Prime Extragalactic Areas for Reionization and Lensing Science Program in the Spitzer IRAC Dark Field, we search for F150W and F200W dropouts. In 14.2 arcmin2, we have found eight F150W dropouts and eight F200W dropouts, all brighter than 27.5 mag (the brightest being ∼24 mag) in the band to the red side of the break. As they are detected in multiple bands, these must be real objects. Their nature, however, is unclear, and characterizing their properties is important for realizing the full potential of JWST. If the observed color decrements are due to the Lyman break, these objects should be atz≳ 11.7 andz≳ 15.4, respectively. The color diagnostics show that at least four F150W dropouts are far away from the usual contaminators encountered in dropout searches (red galaxies at much lower redshifts or brown dwarf stars). While the diagnostics of the F200W dropouts are less certain due to the limited number of passbands, at least one of them is likely not a known type of contaminant, and the rest are consistent with either high-redshift galaxies with evolved stellar populations or old galaxies atz≈ 3–8. If a significant fraction of our dropouts are indeed atz≳ 12, we have to face the severe problem of explaining their high luminosities and number densities. Spectroscopic identifications of such objects are urgently needed.more » « less
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