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Abstract Comets have similar compositions to interstellar medium ices, suggesting at least some of their molecules may be inherited from an earlier stage of evolution. To investigate the degree to which this might have occurred, we compare the composition of individual comets to that of the well-studied protostellar region IRAS 16293–2422B. We show that the observed molecular abundance ratios in several comets correlate well with those observed in the protostellar source. However, this does not necessarily mean that the cometary abundances are identical to protostellar. We find the abundance ratios of many molecules present in comets are enhanced compared to their protostellar counterparts. For COH molecules, the data suggest higher abundances relative to methanol of more complex species, e.g., HCOOH, CH₃CHO, and HCOOCH₃, are found in comets. For N-bearing molecules, the ratios of nitriles relative to CH₃CN—HC₃N/CH₃CN and HCN/CH₃CN—tend to be enhanced. The abundances of cometary SO and SO₂relative to H₂S are enhanced, whereas OCS/H₂S is reduced. Using a subset of comets with a common set of observed molecules, we suggest a possible means of determining the relative degree to which they retain interstellar ices. This analysis suggests that over 84% of COH-bearing molecules can be explained by the protostellar composition. The possible fraction inherited from the protostellar region is lower for nitrogen molecules, at only 26%–74%. While this is still speculative, especially since few comets have large numbers of observed molecules, it provides a possible route for determining the relative degree to which comets contain disk-processed material. 

Abstract We present Atacama Large Millimeter/submillimeter Array Band 3 data toward five massive young stellar objects (MYSOs), and investigate relationships between unsaturated carbon-chain species and saturated complex organic molecules (COMs). An HC 5 N ( J = 35–34) line has been detected from three MYSOs, where nitrogen (N)-bearing COMs (CH 2 CHCN and CH 3 CH 2 CN) have been detected. The HC 5 N spatial distributions show compact features and match with a methanol (CH 3 OH) line with an upper-state energy around 300 K, which should trace hot cores. The hot regions are more extended around the MYSOs where N-bearing COMs and HC 5 N have been detected compared to two MYSOs without these molecular lines, while there are no clear differences in the bolometric luminosity and temperature. We run chemical simulations of hot-core models with a warm-up stage, and compare with the observational results. The observed abundances of HC 5 N and COMs show good agreements with the model at the hot-core stage with temperatures above 160 K. These results indicate that carbon-chain chemistry around the MYSOs cannot be reproduced by warm carbon-chain chemistry, and a new type of carbon-chain chemistry occurs in hot regions around MYSOs. 

Abstract We present emission maps ( $1.\prime 5\times 1.\prime 5$scale, corresponding to 0.18 pc) of the DCN (J= 2 − 1) and DCO⁺(J= 2 − 1) lines in the 2 mm band toward the Orion KL region obtained with the 2 mm receiver system named B4R installed on the Large Millimeter Telescope. The DCN emission shows a peak at the Orion KL hot core position, whereas no DCO⁺emission has been detected there. The DCO⁺emission shows enhancement at the west side of the hot core, which is well shielded from the UV radiation from OB massive stars in the Trapezium cluster. We have derived the abundance ratio of DCN/DCO⁺at three representative positions where both species have been detected. The gas components withV_LSR≈ 7.5–8.7 km s⁻¹are associated with low abundance ratios of ∼4–6, whereas much higher abundance ratios (∼22–30) are derived for the gas components withV_LSR≈ 9.2–11.6 km s⁻¹. We have compared the observed abundance ratio to our chemical models and found that the observed differences in the DCN/DCO⁺abundance ratios are explained by different densities.