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  1. ; ; ; ; ; ; ( , Cell Reports Physical Science)
    Free, publicly-accessible full text available August 1, 2025
  2. ; ; ; ; ; ; ; ( , The Journal of Organic Chemistry)
    Free, publicly-accessible full text available May 17, 2025
  3. ; ; ; ; ; ; ; ; ; ; et al ( , Green Synthesis and Catalysis)
    Free, publicly-accessible full text available April 1, 2025
  4. ; ; ; ; ; ; ; ; ; ( , Green Synthesis and Catalysis)
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  5. ; ; ; ; ; ; ( , Green Synthesis and Catalysis)
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  6. ; ; ; ; ; ; ; ; ( , The Journal of Organic Chemistry)
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  7. ; ; ; ; ; ; ; ; ; ; et al ( , Green Synthesis and Catalysis)
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  8. ; ; ; ; ; ; ; ; ; ; et al ( , The Journal of Organic Chemistry)
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  9. ; ; ; ; ; ( , Organic Chemistry Frontiers)
    Enantioenriched azaarylmethyl amine derivatives are useful building blocks in synthetic and medicinal chemistry. To access these valuable motifs, an enantioselective palladium-catalyzed benzylation of azaarylmethyl amine pronucleophiles is introduced. Of note, this is a rare application of asymmetric (2-naphthyl)methylation of pro-nucleophiles with high p K a values (p K a ≈ 34 in DMSO). Control experiments support the notion that the coordination of Li + to the azaaryl nitrogen plays a critical role in the substitution process. With this procedure, enantioenriched (2-naphthyl)methylene azaarylmethyl amines with a variety of azaaryl groups (pyridyl, pyrazine, quinoxaline and isoquinoline) and cyclic and acyclic amines are readily obtained with good yields and enantioselectivities up to 99%. 
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  10. ; ; ; ; ; ; ; ( , Organic Chemistry Frontiers)
    Azaindoles and azaindolines are important core structures in pharmaceuticals and natural products, which have found wide applications in the field of medicinal chemistry. In this study, we developed a novel one-pot method for selectively synthesizing 7-azaindoles and 7-azaindolines, which can be generated by reactions between the readily available 2-fluoro-3-methylpyridine and arylaldehydes. The chemoselectivity is counterion dependent, with LiN(SiMe 3 ) 2 generating 7-azaindolines and KN(SiMe 3 ) 2 furnishing 7-azaindoles. A range of substituents can be introduced under these conditions, providing handles for further elaboration and functionalization. 
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