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Abstract Anthropogenic greenhouse gas emissions significantly impact the middle and upper atmosphere. They cause cooling and thermal shrinking and affect the atmospheric structure. Atmospheric contraction results in changes in key atmospheric features, such as the stratopause height or the peak ionospheric electron density, and also results in reduced thermosphere density. These changes can impact, among others, the lifespan of objects in low Earth orbit, refraction of radio communication and GPS signals, and the peak altitudes of meteoroids entering the Earth's atmosphere. Given this, there is a critical need for observational capabilities to monitor the middle and upper atmosphere. Equally important is the commitment to maintaining and improving long‐term, homogeneous data collection. However, capabilities to observe the middle and upper atmosphere are decreasing rather than improving. 

Magnesium oxide (MgO) is a major component of the Earth’s mantle and is expected to play a similar role in the mantles of large rocky exoplanets. At extreme pressures, MgO transitions from the NaClB1 crystal structure to a CsClB2 structure, which may have implications for exoplanetary deep mantle dynamics. In this study, we constrain the phase diagram of MgO with laser-compression along the shock Hugoniot, with simultaneous measurements of crystal structure, density, pressure, and temperature. We identify theB1 toB2 phase transition between 397 and 425 gigapascal (around 9700 kelvin), in agreement with recent theory that accounts for phonon anharmonicity. From 425 to 493 gigapascal, we observe a mixed-phase region of B1 and B2 coexistence. The transformation follows the Watanabe-Tokonami-Morimoto mechanism. Our data are consistent withB2-liquid coexistence above 500 gigapascal and complete melting at 634 gigapascal. This study bridges the gap between previous theoretical and experimental studies, providing insights into the timescale of this phase transition. 

Self-assembled materials capable of modulating their assembly properties in response to specific enzymes play a pivotal role in advancing ‘intelligent’ encapsulation platforms for biotechnological applications. Here, we introduce a previously unreported class of synthetic nanomaterials that programmatically interact with histone deacetylase (HDAC) as the triggering stimulus for disassembly. These nanomaterials consist of co-polypeptides comprising poly (acetyl L-lysine) and poly(ethylene glycol) blocks. Under neutral pH conditions, they self-assemble into particles. However, their stability is compromised upon exposure to HDACs, depending on enzyme concentration and exposure time. Our investigation, utilizing HDAC8 as the model enzyme, revealed that the primary mechanism behind disassembly involves a decrease in amphiphilicity within the block copolymer due to the deacetylation of lysine residues within the particles’ hydrophobic domains. To elucidate the response mechanism, we encapsulated a fluorescent dye within these nanoparticles. Upon incubation with HDAC, the nanoparticle structure collapsed, leading to controlled release of the dye over time. Notably, this release was not triggered by denatured HDAC8, other proteolytic enzymes like trypsin, or the co-presence of HDAC8 and its inhibitor. We further demonstrated the biocompatibility and cellular effects of these materials and conducted a comprehensive computational study to unveil the possible interaction mechanism between enzymes and particles. By drawing parallels to the mechanism of naturally occurring histone proteins, this research represents a pioneering step toward developing functional materials capable of harnessing the activity of epigenetic enzymes such as HDACs. 

This study introduces novel constraints on the free streaming of thermal relic warm dark matter (WDM) from Lyman- $\alpha$forest flux power spectra. Our analysis utilizes a high resolution, high redshift sample of quasar spectra observed using the HIRES and UVES spectrographs ( $z=4.2–5.0$). We employ a Bayesian inference framework and a simulation-based likelihood that encompasses various parameters including the free streaming of dark matter, cosmological parameters, the thermal history of the intergalactic medium, and inhomogeneous reionization to establish lower limits on the mass of a thermal relic WDM particle of 5.7 keV (at 95% CL). This result surpasses previous limits from the Lyman- $\alpha$forest through reduction of the measured uncertainties due to a larger statistical sample and by measuring clustering to smaller scales ( $k_{\max }=0.2{\mathrm{km}}^{-1}\mathrm{s}$). The approximately two-fold improvement due to the expanded statistical sample suggests that the effectiveness of Lyman- $\alpha$forest constraints on WDM models at high redshifts are limited by the availability of high quality quasar spectra. Restricting the analysis to comparable scales and thermal history priors as in prior studies ( $k_{\max }<0.1{\mathrm{km}}^{-1}\mathrm{s}$) lowers the bound on the WDM mass to 4.1 keV. As the precision of the measurements increases, it becomes crucial to examine the instrumental and modeling systematics. On the modeling front, we argue that the impact of the thermal history uncertainty on the WDM particle mass constraint has diminished due to improved independent observations. At the smallest scales, the primary source of modeling systematic arises from the structure in the peculiar velocity of the intergalactic medium and inhomogeneous reionization. Published by the American Physical Society2024 

ABSTRACT Intervening metal absorbers in quasar spectra at z > 6 can be used as probes to study the chemical enrichment of the Universe during the Epoch of Reionization. This work presents the comoving line densities (dn/dX) of low-ionization absorbers, namely, Mg ii (2796 Å), C ii (1334 Å), and O  i (1302 Å) across 2 < z < 6 using the E-XQR-30 metal absorber catalogue prepared from 42 XSHOOTER quasar spectra at 5.8 < z < 6.6. Here, we analyse 280 Mg ii (1.9 < z < 6.4), 22 C ii (5.2 < z < 6.4), and 10 O i (5.3 < z < 6.4) intervening absorbers, thereby building up on previous studies with improved sensitivity of 50 per cent completeness at an equivalent width of W > 0.03 Å. For the first time, we present the comoving line densities of 131 weak (W < 0.3 Å) intervening Mg ii absorbers at 1.9 < z < 6.4 which exhibit constant evolution with redshift similar to medium (0.3 < W < 1.0 Å) absorbers. However, the cosmic mass density of Mg ii – dominated by strong Mg ii systems – traces the evolution of global star formation history from redshift 1.9 to 5.5. E-XQR-30 also increases the absorption path-length by a factor of 50 per cent for C ii and O i whose line densities show a rising trend towards z > 5, in agreement with previous works. In the context of a decline in the metal enrichment of the Universe at z > 5, the overall evolution in the incidence rates of absorption systems can be explained by a weak – possibly soft fluctuating – ultraviolet background. Our results, thereby, provide evidence for a late reionization continuing to occur in metal-enriched and therefore, biased regions in the Universe. 

Context.Photonic lanterns (PLs) are waveguide devices enabling high-throughput single-mode spectroscopy and high angular resolution. Aims.We aim to present the first on-sky demonstration of a PL operating in visible light, to measure its throughput and assess its potential for high-resolution spectroscopy of compact objects. Methods.We used the SCExAO instrument (a double-stage extreme adaptive optics system installed at the Subaru Telescope) and FIRST mid-resolution spectrograph (R 3000) to test the visible capabilities of the PL on internal source and on-sky observations. Results.The best averaged coupling efficiency over the PL field of view was measured at 51% ± 10%, with a peak at 80%. We also investigated the relationship between coupling efficiency and the Strehl ratio for a PL, comparing them with those of a single-mode fiber (SMF). Findings show that in the adaptive optics regime a PL offers a better coupling efficiency performance than an SMF, especially in the presence of low-spatial-frequency aberrations. We observed Ikiiki (αLeo –m_R= 1.37) and ‘Aua (αOri –m_R= −1.17) at a frame rate of 200 Hz. Under median seeing conditions (about 1 arcsec measured in theHband) and large tip or tilt residuals (over 20 mas), we estimated an average light coupling efficiency of 14.5% ± 7.4%, with a maximum of 42.8% at 680 nm. We were able to reconstruct both star’s spectra, containing various absorption lines. Conclusions.The successful demonstration of this device opens new possibilities in terms of high-throughput single-mode fiber-fed spectroscopy in the visible. The demonstrated on-sky coupling efficiency performance would not have been achievable with a single SMF injection setup under similar conditions, partly because the residual tip or tilt alone exceeded the field of view of a visible SMF (18 mas at 700 nm). This emphasizes the enhanced resilience of PL technology to such atmospheric disturbances. The additional capabilities in high angular resolution are also promising but still have to be demonstrated in a forthcoming investigation. 

Abstract Extreme (>20 nT/s) geomagnetic disturbances (GMDs, also denoted as MPEs—magnetic perturbation events)—impulsive nighttime disturbances with time scale ∼5–10 min, have sufficient amplitude to cause bursts of geomagnetically induced currents (GICs) that can damage technical infrastructure. In this study, we present occurrence statistics for extreme GMD events from five stations in the MACCS and AUTUMNX magnetometer arrays in Arctic Canada at magnetic latitudes ranging from 65° to 75°. We report all large (≥6 nT/s) and extreme GMDs from these stations from 2011 through 2022 to analyze variations of GMD activity over a full solar cycle and compare them to those found in three earlier studies. GMD activity between 2011 and 2022 did not closely follow the sunspot cycle, but instead was lowest during its rising phase and maximum (2011–2014) and highest during the early declining phase (2015–2017). Most of these GMDs, especially the most extreme, were associated with high‐speed solar wind streams (Vsw >600 km/s) and steady solar wind pressure. All extreme GMDs occurred within 80 min after substorm onsets, but few within 5 min. Multistation data often revealed a poleward progression of GMDs, consistent with a tailward retreat of the magnetotail reconnection region. These observations indicate that extreme GIC hazard conditions can occur for a variety of solar wind drivers and geomagnetic conditions, not only for fast‐coronal mass ejection driven storms.