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The tandem solar cell presents a potential solution to surpass the Shockley–Queisser limit observed in single-junction solar cells. However, creating a tandem device that is both cost-effective and highly efficient poses a significant challenge. In this study, we present proof of concept for a four-terminal (4T) tandem solar cell utilizing a wide bandgap (1.6–1.8 eV) perovskite top cell and a narrow bandgap (1.2 eV) antimony selenide (Sb2Se3) bottom cell. Using a one-dimensional (1D) solar cell capacitance simulator (SCAPS), our calculations indicate the feasibility of this architecture, projecting a simulated device performance of 23% for the perovskite/Sb2Se3 4T tandem device. To validate this, we fabricated two wide bandgap semitransparent perovskite cells with bandgaps of 1.6 eV and 1.77 eV, respectively. These were then mechanically stacked with a narrow bandgap antimony selenide (1.2 eV) to create a tandem structure, resulting in experimental efficiencies exceeding 15%. The obtained results demonstrate promising device performance, showcasing the potential of combining perovskite top cells with the emerging, earth-abundant antimony selenide thin film solar technology to enhance overall device efficiency.more » « less
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Vijayaraghavan, S.N.; Wall, Jacob; Menon, Harigovind G.; Duan, Xiaomeng; Guo, Liping; Amin, Al; Han, Xiao; Kong, Lingyan; Zheng, Yufeng; Li, Lin; et al (, Solar Energy)
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Guo, Liping; Vijayaraghavan, S.N.; Duan, Xiaomeng; Menon, Harigovind G.; Wall, Jacob; Kong, Lingyan; Gupta, Subhadra; Li, Lin; Yan, Feng (, Solar Energy)null (Ed.)
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