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ABSTRACT Intermittent streams are prevalent worldwide, yet the understanding of drivers of their changing flow patterns remains incomplete. We examined hydrological changes spanning four decades (1982–2020) in Kings Creek, an intermittent grassland stream within the Konza Prairie Biological Station in Kansas, USA. We analysed streamflow data from a US Geological Survey gauge on Kings Creek and three upstream Long Term Ecological Reasearch (LTER) sub‐watersheds with annual, biennial or quadrennial burn frequencies and linked trajectories of woody encroachment to increased evapotranspiration and changes in streamflow. Riparian woody cover doubled in the annually and biannually burned sub‐watersheds and sevenfold in the quadrennially burned watersheds. We observed significant decreases (84%) in daily discharge and number of annual flow days (55%) at the downstream USGS Kings Creek gauge, with similar changes in the LTER sub‐watersheds. The changing riparian cover, propelled by the regional expansion of woody plants, contributed to decreased streamflow by amplifying actual evapotranspiration (ET). Seasonal assessments underscored the critical influence of late summer conditions (July–September), under which increases in ET were linked to rising temperatures and increased evapotranspiration by riparian cover. Our results highlight the significant hydrological impacts of woody encroachment in grasslands and emphasize the importance of long‐term ecohydrological monitoring in unravelling the interplay between climate and vegetation as controls on the hyper‐variable flow patterns in this intermittent stream. Predicting and managing hydrological impacts on the flow of intermittent grassland rivers and streams worldwide requires accounting for the effects of accelerating woody encroachment. 

Hybrid complexes incorporating synthetic Mn-porphyrins into an artificial four-helix bundle domain of bacterial reaction centers created a system to investigate new electron transfer pathways. The reactions were initiated by illumination of the bacterial reaction centers, whose primary photochemistry involves electron transfer from the bacteriochlorophyll dimer through a series of electron acceptors to the quinone electron acceptors. Porphyrins with diphenyl, dimesityl, or fluorinated substituents were synthesized containing either Mn or Zn. Electrochemical measurements revealed potentials for Mn(III)/Mn(II) transitions that are ~ 0.4 V higher for the fluorinated Mn-porphyrins than the diphenyl and dimesityl Mn-porphyrins. The synthetic porphyrins were introduced into the proteins by binding to a four-helix bundle domain that was genetically fused to the reaction center. Light excitation of the bacteriochlorophyll dimer of the reaction center resulted in new derivative signals, in the 400 to 450 nm region of light-minus-dark spectra, that are consistent with oxidation of the fluorinated Mn(II) porphyrins and reduction of the diphenyl and dimesityl Mn(III) porphyrins. These features recovered in the dark and were not observed in the Zn(II) porphyrins. The amplitudes of the signals were dependent upon the oxidation/reduction midpoint potentials of the bacteriochlorophyll dimer. These results are interpreted as photo-induced charge-separation processes resulting in redox changes of the Mn-porphyrins, demonstrating the utility of the hybrid artificial reaction center system to establish design guidelines for novel electron transfer reactions. 

The integration of Computational Thinking (CT) into K-12 education has gained significance in recent years as the field of education experiences the need to equip students with essential skills for the 21st century. This case study focused on two sequencing activities, involving plugged and unplugged tasks, conducted with four children aged four to seven, spanning pre-kindergarten to second grade. The central research question guiding the study was: "What computational thinking (CT) skills were demonstrated by K-2 students as they engaged in two different sequencing tasks?" The study identified competencies in sequencing, reverse sequencing, debugging, pattern recognition, and problem decomposition. The findings suggest that both unplugged and plugged sequencing tasks provide age-appropriate entry points for young children to develop various CT competencies. Furthermore, the study highlights the potential for plugged and unplugged sequencing tasks to be integrated into early childhood classroom activities, offering a practical approach to promoting CT skills in young learners. 

Abstract Recent multi-point measurements, in particular from the Magnetospheric Multiscale (MMS) spacecraft, have advanced the understanding of micro-scale aspects of magnetic reconnection. In addition, the MMS mission, as part of the Heliospheric System Observatory, combined with recent advances in global magnetospheric modeling, have furthered the understanding of meso- and global-scale structure and consequences of reconnection. Magnetic reconnection at the dayside magnetopause and in the magnetotail are the drivers of the global Dungey cycle, a classical picture of global magnetospheric circulation. Some recent advances in the global structure and consequences of reconnection that are addressed here include a detailed understanding of the location and steadiness of reconnection at the dayside magnetopause, the importance of multiple plasma sources in the global circulation, and reconnection consequences in the magnetotail. These advances notwithstanding, there are important questions about global reconnection that remain. These questions focus on how multiple reconnection and reconnection variability fit into and complicate the Dungey Cycle picture of global magnetospheric circulation. 

SN 2020zbf is a hydrogen-poor superluminous supernova (SLSN) atz = 0.1947 that shows conspicuous C IIfeatures at early times, in contrast to the majority of H-poor SLSNe. Its peak magnitude isM_g = −21.2 mag and its rise time (≲26.4 days from first light) places SN 2020zbf among the fastest rising type I SLSNe. We used spectra taken from ultraviolet (UV) to near-infrared wavelengths to identify spectral features. We paid particular attention to the C IIlines as they present distinctive characteristics when compared to other events. We also analyzed UV and optical photometric data and modeled the light curves considering three different powering mechanisms: radioactive decay of⁵⁶Ni, magnetar spin-down, and circumstellar medium (CSM) interaction. The spectra of SN 2020zbf match the model spectra of a C-rich low-mass magnetar-powered supernova model well. This is consistent with our light curve modeling, which supports a magnetar-powered event with an ejecta massM_ej = 1.5 M_⊙. However, we cannot discard the CSM-interaction model as it may also reproduce the observed features. The interaction with H-poor, carbon-oxygen CSM near peak light could explain the presence of C IIemission lines. A short plateau in the light curve around 35–45 days after peak, in combination with the presence of an emission line at 6580 Å, can also be interpreted as being due to a late interaction with an extended H-rich CSM. Both the magnetar and CSM-interaction models of SN 2020zbf indicate that the progenitor mass at the time of explosion is between 2 and 5M_⊙. Modeling the spectral energy distribution of the host galaxy reveals a host mass of 10^8.7M_⊙, a star formation rate of 0.24_−0.12^+0.41M_⊙yr⁻¹, and a metallicity of ∼0.4Z_⊙.