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Mass fabrication of molecular spintronics devices (MSDs) can harness the untapped exotic properties of molecules for making the next generation of computers, including quantum computers for the common public. However, since the conceptualization of molecular devices in early 1970, no device fabrication approach has provided answers to major critical device fabrication challenges. The most pressing challenge is the lack of a commercially viable device fabrication approach. This paper show a novel method of utilizing magnetic tunnel junction (MTJ) with a grooved bottom electrode to address MSD fabrication challenges. SMM-like molecules of interest will be bonded along the exposed edges of an MTJ to serve as a device channel. MTJ's insulator serves as an industrially mass-producible spacer between ferromagnetic electrodes and is expected to give >95% MSD yield. We patented this method as P. Tyagi, "Trenched Bottom Electrode and Liftoff based Molecular Devices. U.S. Patent Application No. 16/102,732.," 2020.more » « less
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Instructor-led presentation-based teaching mainly focuses on delivering content. Whereas student active presentations-based teaching approaches require students to take leadership in learning actions. Many teaching and learning strategies were adopted to foster active student participation during in-class learning activities. We developed the student presentation-based effective teaching (SPET) approach in 2014 to make student presentation activity the central element of learning challenging concepts. We have developed several versions to meet the need for teaching small classes (P. Tyagi, "Student Presentation Based Effective Teaching (SPET) Approach for Advanced Courses," in ASME IMECE 2016-66029, V005T06A026), large enrolment classes (P. Tyagi, "Student Presentation Based Teaching (SPET) Approach for Classes With Higher Enrolment," ASME IMECE 2018-88463, V005T07A035), and online teaching during COVID-19. (P. Tyagi, "Second Modified Student Presentation Based Effective Teaching (SPET) Method Tested in COVID-19 Affected Senior Level Mechanical Engineering Course," in ASME IMECE 2020-23615, V009T09A026). The SPET approach has successfully engaged students with varied interests and competence levels in the learning process. SPET approach has also made it possible to cover new topics such as training engineering students about positive intelligence skills to foster lifelong learning aptitude and doing engineering projects in a group setting. However, it was noted that many students who were overwhelmed with parallel academic demands in other courses and different activities were underperforming via SPET-based learning strategies. SPET core functioning depends on the following steps: Step 1: Provide a set of conceptual and topical questions for students to answer individually after self-education from the recommended textbook or course material, Step-2: Group presentations are prepared by the prepared students for in-class discussion, Step-3: Group makes a presentation in class 1-2 weeks after the day of the assignment to seek instructor feedback and to do peer discussion. The instructor noted that students unfamiliar with the new concepts and terminologies in the SPET assignment struggled to respond to questions individually and contribute to the group discussion based on their presentation. Several motivated students who invested time in familiarizing new concepts and terminologies met or exceeded the expectations. However, a significant student population struggled. To alleviate this issue author has implemented a further improvement in SPET approach. This paper reports teaching experiments conducted in MECH 487 Photovoltaic Cells and Solar Thermal Energy System and MECH 462 Design of Energy Systems course. This improvement requires augmenting SPET with instructor-led concept familiarization discussion on the day of issuing the assignment or close to that; for this step instructor utilized exemplary student work from prior SPET-based teaching of the same course. In the survey, many students expressed their views about the improvement and reported introductory discussions were helpful and addressed several reservations and impediments students encountered. This paper will discuss the structure of the new improvement strategy and outcomes-including student feedback and comments.more » « less
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Magnetic tunnel junction (MTJ) can serve as an excellent testbed for connecting Molecule between two ferromagnetic electrodes. A paramagnetic molecule covalently bonded to two ferromagnetic electrodes with two thiol functional groups can produce intriguing transport and magnetic properties. We have chemically bonded paramagnetic molecules between two ferromagnetic electrodes of a MTJ along the exposed side edges. In this paper we discussed the observation of Molecule induced dramatic changes in the magnetic and transport properties of the conventional magnetic tunnel junctions. Paramagnetic molecules were chemically bonded to ferromagnetic electrodes to bridge them across the insulating spacer along the exposed edges. Paramagnetic molecular channels along the tunnel junction edges decreased the overall current, through tunnel barrier and molecular channels, > 5 orders of magnitude below the leakage current of the bare tunnel junction at room temperature. These molecules caused significant changes in the spin density of states due to potential spin filtering effect. Also, paramagnetic molecules produced antiferromagnetic coupling between the affected magnetic electrodes. In this state spin transport in the magnetic tunnel junction based molecular devices plummeted by several orders. It is also noteworthy that our experimental studies provide a platform to connect a vast variety of ferromagnetic leads to the even broader array of high potential molecules such as single molecular magnets, porphyrin, and single ion molecules. The strength of exchange coupling between ferromagnetic electrodes and molecules can be tailored by utilizing different tethers and terminal functional groups. The MTJMSD can provide an advanced form of logic and memory devices, including a testbed for the Molecule based quantum computation devices. Future study about the interaction between molecular magnets and ferromagnets and interaction of thiol ended alkanes with ferromagnets will be of very valuable. This study indicates the potential of magnetic molecules as a mean to transforming conventional magnetic tunnel junctions and producing unprecedented magnetic and transport properties.more » « less