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Crystals of the title salt, (C8H20N)[Sn(C6H5)3(C2H2O2S)], comprise diisobutylammonium cations and mercaptoacetatotriphenylstannate(IV) anions. The bidentate binding mode of the mercaptoacetate ligand gives rise to a five-coordinated, ionic triphenyltin complex with a distortedcis-trigonal–bipyramidal geometry around the tin atom. In the crystal, charge-assisted ammonium-N—H...O(carboxylate) hydrogen-bonding connects two cations and two anions into a four-ion aggregate. Two positions were resolved for one of the phenyl rings with the major component having a site occupancy factor of 0.60 (3).more » « lessFree, publicly-accessible full text available August 1, 2025
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Horvath, Mikayla L.; Jumbelic, Caylee E.; Burynski, Rosemarie A.; Mistrot, M. Brody; Pike, Robert D.; Smith, Brian J.; Arslan, Hasan (, Chemical Communications)A single crystal growth method for low solubility polycyclic aromatic substrates based on competitive host–guest equilibria is developed.more » « less
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Barham, Alexander; Neu, Justin; Canter, Cathleen L.; Pike, Robert D.; Li, Yumin; Huo, Shouquan (, Organometallics)
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Masonheimer, Carly L.; Atwood, Madeleine G.; Hartzell, Susan E.; Reph, Erin A.; Pike, Robert D.; Stockland, Robert A. (, Organometallics)