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Ancient texts and archaeological evidence indicate substantial lead exposure during antiquity that potentially impacted human health. Although lead exposure routes were many and included the use of glazed tablewares, paints, cosmetics, and even intentional ingestion, the most significant for the nonelite, rural majority of the population may have been through background air pollution from mining and smelting of silver and lead ores that underpinned the Roman economy. Here, we determined potential health effects of this air pollution using Arctic ice core measurements of Roman-era lead pollution, atmospheric modeling, and modern epidemiology-based relationships between air concentrations, blood lead levels (BLLs), and cognitive decline. Findings suggest air lead concentrations exceeded 150 ng/m³near metallurgical emission sources, with average enhancements of >1.0 ng/m³over Europe during the Pax Romana apogee of the Roman Empire. The result was blood lead enhancements in young children of about 2.4 µg/dl above an estimated Neolithic background of 1.0 µg/dl, leading to widespread cognitive decline including a 2.5-to-3 point reduction in intelligence quotient throughout the Roman Empire. 

Polar ice cores and historical records evidence a large-magnitude volcanic eruption in 1831 CE. This event was estimated to have injected ~13 Tg of sulfur (S) into the stratosphere which produced various atmospheric optical phenomena and led to Northern Hemisphere climate cooling of ~1 °C. The source of this volcanic event remains enigmatic, though one hypothesis has linked it to a modest phreatomagmatic eruption of Ferdinandea in the Strait of Sicily, which may have emitted additional S through magma–crust interactions with evaporite rocks. Here, we undertake a high-resolution multiproxy geochemical analysis of ice-core archives spanning the 1831 CE volcanic event. S isotopes confirm a major Northern Hemisphere stratospheric eruption but, importantly, rule out significant contributions from external evaporite S. In multiple ice cores, we identify cryptotephra layers of low K andesite-dacite glass shards occurring in summer 1831 CE and immediately prior to the stratospheric S fallout. This tephra matches the chemistry of the youngest Plinian eruption of Zavaritskii, a remote nested caldera on Simushir Island (Kurils). Radiocarbon ages confirm a recent (<300 y) eruption of Zavaritskii, and erupted volume estimates are consistent with a magnitude 5 to 6 event. The reconstructed radiative forcing of Zavaritskii (−2 ± 1 W m⁻²) is comparable to the 1991 CE Pinatubo eruption and can readily account for the climate cooling in 1831–1833 CE. These data provide compelling evidence that Zavaritskii was the source of the 1831 CE mystery eruption and solve a confounding case of multiple closely spaced observed and unobserved volcanic eruptions. 

Abstract Existing global volcanic radiative aerosol forcing estimates portray the period 700 to 1000 as volcanically quiescent, void of major volcanic eruptions. However, this disagrees with proximal Icelandic geological records and regional Greenland ice-core records of sulfate. Here, we use cryptotephra analyses, high-resolution sulfur isotope analyses, and glaciochemical volcanic tracers on an array of Greenland ice cores to characterise volcanic activity and climatically important sulfuric aerosols across the period 700 to 1000. We identify a prolonged episode of volcanic sulfur dioxide emissions (751–940) dominated by Icelandic volcanism, that we term the Icelandic Active Period. This period commences with the Hrafnkatla episode (751–763), which coincided with strong winter cooling anomalies across Europe. This study reveals an important contribution of prolonged volcanic sulfate emissions to the pre-industrial atmospheric aerosol burden, currently not considered in existing forcing estimates, and highlights the need for further research to disentangle their associated climate feedbacks. 

Abstract The Eldgjá eruption is the largest basalt lava flood of the Common Era. It has been linked to a major ice‐core sulfur (S) spike in 939–940 CE and Northern Hemisphere summer cooling in 940 CE. Despite its magnitude and potential climate impacts, uncertainties remain concerning the eruption timeline, atmospheric dispersal of emitted volatiles, and coincident volcanism in Iceland and elsewhere. Here, we present a comprehensive analysis of Greenland ice‐cores from 936 to 943 CE, revealing a complex volatile record and cryptotephra with numerous geochemical populations. Transitional alkali basalt tephra matching Eldgjá are found in 939–940 CE, while tholeiitic basalt shards present in 936/937 CE and 940/941 CE are compatible with contemporaneous Icelandic eruptions from Grímsvötn and Bárðarbunga‐Veiðivötn systems (including V‐Sv tephra). We also find four silicic tephra populations, one of which we link to the Jala Pumice of Ceboruco (Mexico) at 941 ± 1 CE. Triple S isotopes, Δ³³S, spanning 936–940 CE are indicative of upper tropospheric/lower stratospheric transport of aerosol sourced from the Icelandic fissure eruptions. However, anomalous Δ³³S (down to −0.4‰) in 940–941 CE evidence stratospheric aerosol transport consistent with summer surface cooling revealed by tree‐ring reconstructions. Tephra associated with the anomalous Δ³³S have a variety of compositions, complicating the attribution of climate cooling to Eldgjá alone. Nevertheless, our study confirms a major S emission from Eldgjá in 939–940 CE and implicates Eldgjá and a cluster of eruptions as triggers of summer cooling, severe winters, and privations in ∼940 CE. 

Abstract Tephra is a unique volcanic product with an unparalleled role in understanding past eruptions, long-term behavior of volcanoes, and the effects of volcanism on climate and the environment. Tephra deposits also provide spatially widespread, high-resolution time-stratigraphic markers across a range of sedimentary settings and thus are used in numerous disciplines (e.g., volcanology, climate science, archaeology). Nonetheless, the study of tephra deposits is challenged by a lack of standardization that inhibits data integration across geographic regions and disciplines. We present comprehensive recommendations for tephra data gathering and reporting that were developed by the tephra science community to guide future investigators and to ensure that sufficient data are gathered for interoperability. Recommendations include standardized field and laboratory data collection, reporting and correlation guidance. These are organized as tabulated lists of key metadata with their definition and purpose. They are system independent and usable for template, tool, and database development. This standardized framework promotes consistent documentation and archiving, fosters interdisciplinary communication, and improves effectiveness of data sharing among diverse communities of researchers. 

Abstract. Volcanic fallout in polar ice sheets provides important opportunities to date and correlate ice-core records as well as to investigate theenvironmental impacts of eruptions. Only the geochemical characterization of volcanic ash (tephra) embedded in the ice strata can confirm the sourceof the eruption, however, and is a requisite if historical eruption ages are to be used as valid chronological checks on annual ice layercounting. Here we report the investigation of ash particles in a Greenland ice core that are associated with a volcanic sulfuric acid layer previouslyattributed to the 79 CE eruption of Vesuvius. Major and trace element composition of the particles indicates that the tephra does not derive fromVesuvius but most likely originates from an unidentified eruption in the Aleutian arc. Using ash dispersal modeling, we find that only an eruptionlarge enough to include stratospheric injection is likely to account for the sizable (24–85 µm) ash particles observed in the Greenlandice at this time. Despite its likely explosivity, this event does not appear to have triggered significant climate perturbations, unlike some otherlarge extratropical eruptions. In light of a recent re-evaluation of the Greenland ice-core chronologies, our findings further challenge the previousassignation of this volcanic event to 79 CE. We highlight the need for the revised Common Era ice-core chronology to be formally accepted by the widerice-core and climate modeling communities in order to ensure robust age linkages to precisely dated historical and paleoclimate proxy records. 

Abstract. Volcanic eruptions are a key source of climatic variability, andreconstructing their past impact can improve our understanding of theoperation of the climate system and increase the accuracy of future climateprojections. Two annually resolved and independently dated palaeoarchives –tree rings and polar ice cores – can be used in tandem to assess thetiming, strength and climatic impact of volcanic eruptions over the past∼ 2500 years. The quantification of post-volcanic climateresponses, however, has at times been hampered by differences betweensimulated and observed temperature responses that raised questions regardingthe robustness of the chronologies of both archives. While manychronological mismatches have been resolved, the precise timing and climaticimpact of two major sulfate-emitting volcanic eruptions during the 1450s CE, including the largest atmospheric sulfate-loading event in the last 700 years, have not been constrained. Here we explore this issue through acombination of tephrochronological evidence and high-resolution ice-corechemistry measurements from a Greenland ice core, the TUNU2013 record. We identify tephra from the historically dated 1477 CE eruption of theIcelandic Veiðivötn–Bárðarbunga volcanic system in directassociation with a notable sulfate peak in TUNU2013 attributed to thisevent, confirming that this peak can be used as a reliable and precisetime marker. Using seasonal cycles in several chemical elements and 1477 CEas a fixed chronological point shows that ages of 1453 CE and 1458 CE can beattributed, with high precision, to the start of two other notablesulfate peaks. This confirms the accuracy of a recent Greenland ice-corechronology over the middle to late 15th century and corroborates thefindings of recent volcanic reconstructions from Greenland and Antarctica.Overall, this implies that large-scale Northern Hemisphere climatic coolingaffecting tree-ring growth in 1453 CE was caused by a Northern Hemispherevolcanic eruption in 1452 or early 1453 CE, and then a Southern Hemisphereeruption, previously assumed to have triggered the cooling, occurred laterin 1457 or 1458 CE. The direct attribution of the 1477 CE sulfate peak to the eruption ofVeiðivötn, one of the most explosive from Iceland in the last 1200 years, also provides the opportunity to assess the eruption's climaticimpact. A tree-ring-based reconstruction of Northern Hemisphere summertemperatures shows a cooling in the aftermath of the eruption of −0.35 ∘C relative to a 1961–1990 CE reference period and−0.1 ∘C relative to the 30-year period around the event, as well as arelatively weak and spatially incoherent climatic response in comparison tothe less explosive but longer-lasting Icelandic Eldgjá 939 CE and Laki1783 CE eruptions. In addition, the Veiðivötn 1477 CE eruptionoccurred around the inception of the Little Ice Age and could be used as achronostratigraphic marker to constrain the phasing and spatial variabilityof climate changes over this transition if it can be traced in moreregional palaeoclimatic archives. 

Abstract. The 852/3 CE eruption of Mount Churchill, Alaska, was one of the largestfirst-millennium volcanic events, with a magnitude of 6.7 (VEI 6) and atephra volume of 39.4–61.9 km3 (95 % confidence). The spatial extent of the ash fallout from this event is considerable and the cryptotephra (White River Ash east; WRAe) extends as far as Finland and Poland. Proximal ecosystem and societal disturbances have been linked with this eruption; however, wider eruption impacts on climate and society are unknown. Greenland ice core records show that the eruption occurred in winter 852/3 ± 1 CE and that the eruption is associated with a relatively moderate sulfate aerosol loading but large abundances of volcanic ash and chlorine. Here we assess the potential broader impact of this eruption using palaeoenvironmental reconstructions, historical records and climate model simulations. We also use the fortuitous timing of the 852/3 CE Churchill eruption and its extensively widespread tephra deposition of the White River Ash (east) (WRAe) to examine the climatic expression of the warm Medieval Climate Anomaly period (MCA; ca. 950–1250 CE) from precisely linked peatlands in the North Atlantic region. The reconstructed climate forcing potential of the 852/3 CE Churchill eruptionis moderate compared with the eruption magnitude, but tree-ring-inferredtemperatures report a significant atmospheric cooling of 0.8 ∘Cin summer 853 CE. Modelled climate scenarios also show a cooling in 853 CE, although the average magnitude of cooling is smaller (0.3 ∘C). The simulated spatial patterns of cooling are generally similar to those generated using the tree-ring-inferred temperature reconstructions. Tree-ring-inferred cooling begins prior to the date of the eruption suggesting that natural internal climate variability may have increased the climate system's susceptibility to further cooling. The magnitude of the reconstructed cooling could also suggest that the climate forcing potential of this eruption may be underestimated, thereby highlighting the need for greater insight into, and consideration of, the role of halogens and volcanic ash when estimating eruption climate forcing potential. Precise comparisons of palaeoenvironmental records from peatlands acrossNorth America and Europe, facilitated by the presence of the WRAe isochron,reveal no consistent MCA signal. These findings contribute to the growingbody of evidence that characterises the MCA hydroclimate astime-transgressive and heterogeneous rather than a well-defined climaticperiod. The presence of the WRAe isochron also demonstrates that nolong-term (multidecadal) climatic or societal impacts from the 852/3 CEChurchill eruption were identified beyond areas proximal to the eruption.Historical evidence in Europe for subsistence crises demonstrate a degree of temporal correspondence on interannual timescales, but similar events were reported outside of the eruption period and were common in the 9thcentury. The 852/3 CE Churchill eruption exemplifies the difficulties ofidentifying and confirming volcanic impacts for a single eruption, even whenthe eruption has a small age uncertainty.