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Forging Strong Co–C(sp ² ) Bonds in Co-Macrocycle: Mono- and Bis-Aryl Complexes of Co ^III (TIM)

https://doi.org/10.1021/acs.organomet.5c00097

McGuire, Kyle J; Ebarb, Austin J; Gautam, Prakhar; Ren, Tong (July 2025, Organometallics)

Free, publicly-accessible full text available July 14, 2026
Fe(III)(TIM) Bis-Aryl Complexes: Molecular and Electronic Structures and Metal–Ligand/Ligand–Metal Charge-Transfer Spectra

https://doi.org/10.1021/acs.inorgchem.5c00989

Gautam, Prakhar; Hassan, Fathima_Dilki S; Tierney, David L; DeLancey, Stephanie S; Clendening, Reese A; Ren, Tong (June 2025, Inorganic Chemistry)

Free, publicly-accessible full text available June 9, 2026
Trans influence of cyanide on the structural and electronic properties of a series of organocobalt ^III (TIM) complexes

https://doi.org/10.1039/D4NJ02364A

Rodriguez_Segura, Leobardo; Ren, Tong (July 2024, New Journal of Chemistry)

The mutualtransinfluence of the axial ligands in a series oftrans-[RCo(TIM)(CN)]⁺complexes was investigated using X-ray diffraction studies, absorption and FTIR spectroscopies, and cyclic voltammetry experiments.
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M(TEIM) complexes with M as Co and Fe: Analogues of classic M(TIM)

https://doi.org/10.1016/j.poly.2024.117101

Roos, Jeremy J; Gautam, Prakhar; Martin, Maximilian P; Rodriguez_Segura, Leobardo; Poore, Andrew T; Tian, Shiliang; Adeniyi, Aanuoluwapo E; Andrews, Justin L; Ren, Tong (October 2024, Polyhedron)

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Synthesis and Characterization of Co ^III (TIM) Complexes Bearing Alkenyl or 1-Aza-2-cobalt-cyclopropane Moieties

https://doi.org/10.1021/acs.organomet.4c00113

Rodriguez_Segura, Leobardo; McGuire, Kyle J; Raghavan, Adharsh; Roos, Jeremy J; Ren, Tong (May 2024, Organometallics)

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Fe(III) Bis-Alkynyls Supported by the TIM Macrocycle: Molecular and Electronic Structures and Altering the Nature of Charge Transfer Transitions through Reduction

https://doi.org/10.1021/acs.organomet.4c00015

Gautam, Prakhar; Clendening, Reese A; Poore, Andrew T; Tian, Shiliang; Ren, Tong (March 2024, Organometallics)

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Further Exploration of Aza-Cobalt-Cyclobutenes on Co ^III (TIM) Complexes: Reactivity and Spectroelectrochemistry

https://doi.org/10.1021/acs.organomet.2c00557

Rodriguez Segura, Leobardo; Clendening, Reese A.; Ren, Tong (October 2023, Organometallics)

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Electron transfer rate modulation with mid-IR in butadiyne-bridged donor–bridge–acceptor compounds

https://doi.org/10.1039/D3CP03175F

Mendis, Kasun C; Li, Xiao; Valdiviezo, Jesús; Banziger, Susannah D; Zhang, Peng; Ren, Tong; Beratan, David N; Rubtsov, Igor V (January 2024, Physical Chemistry Chemical Physics)

Controlling electron transfer (ET) processes in donor–bridge–acceptor (DBA) compounds by mid-IR excitation can enhance our understanding of the ET dynamics and may find practical applications in molecular sensing and molecular-scale electronics.
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Nanosecond Metal-to-Ligand Charge-Transfer State in an Fe(II) Chromophore: Lifetime Enhancement via Nested Potentials

https://doi.org/10.1021/jacs.2c13532

Malme, Justin T.; Clendening, Reese A.; Ash, Ryan; Curry, Taylor; Ren, Tong; Vura-Weis, Josh (March 2023, Journal of the American Chemical Society)

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Bis-Alkynyl Complexes of Fe(III) Tetraaza Macrocycles─A Tale of Two Rings

https://doi.org/10.1021/acs.inorgchem.2c01743

Clendening, Reese A.; Zeller, Matthias; Ren, Tong (August 2022, Inorganic Chemistry)

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