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Colloidal PbS/PbCl2 core/shell nanoplatelets were synthesized via wet-chemical methods using lead oleate and lead chloride as lead precursors. The resulting heterostructures consist of a PbS core, a PbCl2 shell, and an intermediate layer of lead sulfochloride alloy. These nanoplatelets exhibit a photoluminescence quantum yield of approximately 20%, nearly an order of magnitude higher than that of unshelled PbS nanoplatelets. Cyclic voltammetry measurements reveal a type-I band alignment between the core and shell. Despite the presence of strong attractive biexciton Auger recombination, as observed in transient absorption spectroscopy, the nanoplatelets achieve amplified spontaneous emission at a low pump threshold of 76 μJ cm–2. Their large lateral dimensions support the spatial distribution of multiple excitons, including repulsive biexcitons, enabling efficient light amplification. 

TRISH (Tree-Ring Integrated System for Hydrology), a new web-based tool for reconstruction of water-balance variables from tree-ring proxies is described. The tool makes use of a mapping application, a global water balance model and R-based reconstruction software. Long time series of water balance variables can be reconstructed by regression or analog statistical methods from tree-ring data uploaded by the user or available in TRISH as previously uploaded public datasets. A predictand hydroclimatic time series averaged or summed over a river basin or arbitrary polygon can be generated interactively by clicking on the map. Control over reconstruction modeling includes optional lagging of predictors, transformation of predictand, and reduction of predictors by principal component analysis. Output includes displayed and downloadable graphics, statistics, and time series. The two-stage reconstruction approach in TRISH allows assessment of the strength of the hydroclimatic signal in individual chronologies in addition to providing a reconstruction based on the tree-ring network. TRISH facilitates the testing of sensitivity of reconstructions to modeling choices and allows a user to explore hydrologic reconstruction in ungauged basins. The R software for reconstruction is available for running offline in the RStudio development environment. TRISH is an open-science resource designed to be shared broadly across the Earth Science research community and to engage water resource management. 

Algorithms are presented that efficiently shape the parity bits of systematic irregular repeat-accumulate (IRA) low-density parity-check (LDPC) codes by following the sequential encoding order of the accumulator. Simulations over additive white Gaussian noise (AWGN) channels with on-off keying show a gain of up to 0.9 dB over uniform signaling. 

Convolutional codes are widely used in many applications. The encoders can be implemented with a simple circuit. Decoding is often accomplished by the Viterbi algorithm or the maximum a-posteriori decoder of Bahl et al. These algorithms are sequential in nature, requiring a decoding time proportional to the message length. For low latency applications this this latency might be problematic. This paper introduces a low-latency decoder for tail-biting convolutional codes TBCCs that processes multiple trellis stages in parallel. The new decoder is designed for hardware with parallel processing capabilities. The overall decoding latency is proportional to the log of the message length. The new decoding architecture is modified into a list decoder, and the list decoding performance can be enhanced by exploiting linearity to expand the search space. Certain modifications to standard TBCCs are supported by the new architecture and improve frame error rate performance.