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Creators/Authors contains: "Rodriguez-Lorenzo, Laura"

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  1. ; ; ; ; ; ; (, Chemical Communications)
    The reactivity of the novel Re( i ) catalyst [Re( C12 Anth-py 2 )(CO) 3 Br] is modulated by its interactions with the covalent organic framework (COF) TFB-BD. The complex catalyzes either reductive etherification, oxidative esterification, or transfer hydrogenation depending on its local environment (embedded in TFB-BD, in homogeneous solution or co-incubated with TFB-BD, respectively). The results highlight that COFs can drastically modulate the reactivity of homogeneous catalysts. 
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