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Abstract Structural disorder has been shown to enhance and modulate magnetic, electrical, dipolar, electrochemical, and mechanical properties of materials. However, the possibility of obtaining novel optical and optoelectronic properties from structural disorder remains an open question. Here, we show unambiguous evidence of disorder — in the form of anisotropic, picoscale atomic displacements — modulating the refractive index tensor and resulting in the giant optical anisotropy observed in BaTiS₃, a quasi‐one‐dimensional hexagonal chalcogenide. Single crystal X‐ray diffraction studies reveal the presence of antipolar displacements of Ti atoms within adjacent TiS₆chains along thec‐axis, and three‐fold degenerate Ti displacements in thea‐bplane.^47/49Ti solid‐state NMR provides additional evidence for those Ti displacements in the form of a three‐horned NMR lineshape resulting from a low symmetry local environment around Ti atoms. We used scanning transmission electron microscopy to directly observe the globally disordered Tia‐bplane displacements and find them to be ordered locally over a few unit cells. First‐principles calculations show that the Tia‐bplane displacements selectively reduce the refractive index along theab‐plane, while having minimal impact on the refractive index along the chain direction, thus resulting in a giant enhancement in the optical anisotropy. By showing a strong connection between structural disorder with picoscale displacements and the optical response in BaTiS₃, this study opens a pathway for designing optical materials with high refractive index and functionalities such as large optical anisotropy and nonlinearity. This article is protected by copyright. All rights reserved 

We report a new type of reflective polarizer based on free-space coupling to surface-plasmon polaritons that has a high extinction ratio and high efficiency at infrared frequencies. 

Thermal emission is the process by which all objects at nonzero temperatures emit light and is well described by the Planck, Kirchhoff, and Stefan–Boltzmann laws. For most solids, the thermally emitted power increases monotonically with temperature in a one-to-one relationship that enables applications such as infrared imaging and noncontact thermometry. Here, we demonstrated ultrathin thermal emitters that violate this one-to-one relationship via the use of samarium nickel oxide (SmNiO 3 ), a strongly correlated quantum material that undergoes a fully reversible, temperature-driven solid-state phase transition. The smooth and hysteresis-free nature of this unique insulator-to-metal phase transition enabled us to engineer the temperature dependence of emissivity to precisely cancel out the intrinsic blackbody profile described by the Stefan–Boltzmann law, for both heating and cooling. Our design results in temperature-independent thermally emitted power within the long-wave atmospheric transparency window (wavelengths of 8 to 14 µm), across a broad temperature range of ∼30 °C, centered around ∼120 °C. The ability to decouple temperature and thermal emission opens a gateway for controlling the visibility of objects to infrared cameras and, more broadly, opportunities for quantum materials in controlling heat transfer.