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TcS 2 undergoes a charge transfer insulator to metal transition above 28 GPa. Laser annealing reveals a kinetically hindered high pressure arsenopyrite phase that is recoverable to ambient. The new phase is similar to the Mn-dichalcogenides rather than the expected Re-dichalcogenides and involves the formation of S–S and Tc–Tc bonds.more » « less
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Fredericks, Scott; Parrish, Kevin; Sayre, Dean; Zhu, Qiang (, Computer Physics Communications)null (Ed.)
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