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The last glacial period was punctuated by cold intervals in the North Atlantic region that culminated in extensive iceberg discharge events. These cold intervals, known as Heinrich Stadials, are associated with abrupt climate shifts worldwide. Here, we present CO₂measurements from the West Antarctic Ice Sheet Divide ice core across Heinrich Stadials 2 to 5 at decadal-scale resolution. Our results reveal multi-decadal-scale jumps in atmospheric CO₂concentrations within each Heinrich Stadial. The largest magnitude of change (14.0 ± 0.8 ppm within 55 ± 10 y) occurred during Heinrich Stadial 4. Abrupt rises in atmospheric CO₂are concurrent with jumps in atmospheric CH₄and abrupt changes in the water isotopologs in multiple Antarctic ice cores, the latter of which suggest rapid warming of both Antarctica and Southern Ocean vapor source regions. The synchroneity of these rapid shifts points to wind-driven upwelling of relatively warm, carbon-rich waters in the Southern Ocean, likely linked to a poleward intensification of the Southern Hemisphere westerly winds. Using an isotope-enabled atmospheric circulation model, we show that observed changes in Antarctic water isotopologs can be explained by abrupt and widespread Southern Ocean warming. Our work presents evidence for a multi-decadal- to century-scale response of the Southern Ocean to changes in atmospheric circulation, demonstrating the potential for dynamic changes in Southern Ocean biogeochemistry and circulation on human timescales. Furthermore, it suggests that anthropogenic CO₂uptake in the Southern Ocean may weaken with poleward strengthening westerlies today and into the future. 

Abstract. Air trapped in polar ice provides unique records of the pastatmospheric composition ranging from key greenhouse gases such as methane(CH4) to short-lived trace gases like ethane (C2H6) andpropane (C3H8). Recently, the comparison of CH4 recordsobtained using different extraction methods revealed disagreements in theCH4 concentration for the last glacial in Greenland ice. Elevatedmethane levels were detected in dust-rich ice core sections measureddiscretely, pointing to a process sensitive to the melt extraction technique. To shed light on the underlying mechanism, we performed targeted experiments and analyzed samples for methane and the short-chain alkanes ethane and propane covering the time interval from 12 to 42 kyr. Here, we report our findings of these elevated alkane concentrations, which scale linearly with the amount of mineral dust within the ice samples. The alkane production happens during the melt extraction step of the classic wet-extraction technique and reaches 14 to 91 ppb of CH4 excess in dusty ice samples. We document for the first time a co-production of excess methane, ethane, and propane, with the observed concentrations for ethane and propane exceeding their past atmospheric background at least by a factor of 10. Independent of the produced amounts, excess alkanes were produced in a fixed molar ratio of approximately 14:2:1, indicating a shared origin. The measured carbon isotopic signature of excess methane is (-47.0±2.9) ‰ and its deuterium isotopic signature is (-326±57) ‰. With the co-production ratios of excess alkanesand the isotopic composition of excess methane we established a fingerprintthat allows us to constrain potential formation processes. This fingerprintis not in line with a microbial origin. Moreover, an adsorption–desorptionprocess of thermogenic gas on dust particles transported to Greenlanddoes not appear very likely. Instead, the alkane pattern appears to beindicative of abiotic decomposition of organic matter as found in soils andplant leaves.