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Surface nanobubbles forming on hydrophobic surfaces in water present an exciting opportunity as potential agents of top-down and bottom-up nanopatterning. The formation and characteristics of surface nanobubbles are strongly influenced by the physical and chemical properties of the substrate. In this study, focused ion beam (FIB) milling is used for the first time to spatially control the nucleation of surface nanobubbles with 75 nm precision. The spontaneous formation of nanobubbles on alternating lines of a self-assembled monolayer (octadecyltrichlorosilane) patterned by FIB is detected by atomic force microscopy. The effect of chemical vs topographical surface heterogeneity on the formation of nanobubbles is investigated by comparing samples with OTS coating applied pre- vs post-FIB patterning. The results confirm that nanoscale FIB-based patterning can effectively control surface nanobubble position by means of chemical heterogeneity. The effect of FIB milling on nanobubble morphology and properties, including contact angle and gas oversaturation, is also reported. Molecular dynamics simulations provide further insight into the effects of FIB amorphization on surface nanobubble formation. Combined experimental and simulation investigations offer insights to guide future nanobubble-based patterning using FIB milling. 

The jetting phenomenon associated with droplet impact upon a hydrophilic micropillared substrate was analyzed in detail using a high-speed camera. Viscosities of the fluids were varied using differing concentrations of glycerol in deionized water. This paper aims to connect similarities between this form of capillary jetting and another well-known jetting phenomenon from the bubble bursting. Both experience a cavity collapse when opposing fluid fronts collide which causes a singularity at the liquid surface, thus leading to the occurrence of jetting. Following processes used to define scaling laws for bubble bursting, a similar approach was taken to derive scaling laws for the dimensionless jet height, jet radius, base height, and radius of the jet base with respect to dimensionless time for the jetting phenomenon associated with the droplet impact. The development of a top droplet before the breakup of the jet also allows the examination of a scaling law for the necking diameter. We find that with the proper scaling factors, the evolution of the jet profile can collapse into a master profile for different fluids and impact velocities. The time dependence of the necking diameter before the jet breakup follows the power law with an exponent of ~2/3. Contrastingly, for other jet parameters such as the radius and height, the power law relationship with time dependence was not found to have a clear pattern that emerged from these studies.