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Cheema, Suraj S. ; Kwon, Daewoong ; Shanker, Nirmaan ; dos Reis, Roberto ; Hsu, Shang-Lin ; Xiao, Jun ; Zhang, Haigang ; Wagner, Ryan ; Datar, Adhiraj ; McCarter, Margaret R. ; et al ( , Nature)
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Barrozo, Petrucio ; Småbråten, Didrik René ; Tang, Yun‐Long ; Prasad, Bhagwati ; Saremi, Sahar ; Ozgur, Rustem ; Thakare, Vishal ; Steinhardt, Rachel A. ; Holtz, Megan E. ; Stoica, Vladimir Alexandru ; et al ( , Advanced Materials)
Abstract Results of switching behavior of the improper ferroelectric LuFeO3are presented. Using a model set of films prepared under controlled chemical and growth‐rate conditions, it is shown that defects can reduce the quasi‐static switching voltage by up to 40% in qualitative agreement with first‐principles calculations. Switching studies show that the coercive field has a stronger frequency dispersion for the improper ferroelectrics compared to a proper ferroelectric such as PbTiO3. It is concluded that the primary structural order parameter controls the switching dynamics of such improper ferroelectrics.