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The isotopic composition of barium (δ¹³⁸Ba) has emerged as a powerful tracer of deep-ocean circulation, water mass provenance, and the oceanic Ba cycle. Although the δ¹³⁸Ba of water masses is primarily controlled by the balance between pelagic barite precipitation and Ba resupply from ocean circulation, questions remain regarding the isotopic offset associated with pelagic barite formation and how the resultant Ba isotope compositions are transmitted through the water column to marine sediments. To address these questions, we conducted a time series study of dissolved, particulate, and sedimentary Ba chemistry in the Gulf of Aqaba (GOA), in the northern Red Sea, from January 2015 to April 2016. These data span significant seasonal changes in hydrography, primary productivity, and aerosol deposition, revealing three principal findings. First, the dissolved Ba chemistry of the GOA is vertically uniform across the time series, largely reflecting water mass advection from the Red Sea, with mean dissolved Ba concentrations of 47.9 ± 4.7 nmol kg⁻¹and mean δ¹³⁸Ba = +0.55‰ ± 0.07‰ (±2 SD,n= 18). Second, despite significant variations in particulate matter composition and flux, the δ¹³⁸Ba of sinking particulate Ba maintained a consistent isotope composition across different depths and over time at +0.09‰ ± 0.06‰ (n= 26). Consequently, these data imply a consistent Ba isotope offset of −0.46‰ ± 0.10‰ (±2 SD) between sinking particulates and seawater. This offset is similar to those determined in previous studies and indicates that it applies to particulates formed across diverse environmental conditions. Third, barite-containing sediment samples deposited in the GOA exhibit δ¹³⁸Ba = +0.34‰ ± 0.03‰, which is offset by approximately +0.2‰ relative to sinking particles. While the specific mechanism driving this offset remains unresolved, our results highlight the importance of performing site-specific proxy validations and exercising careful site selection when applying novel paleoceanographic proxies. 

Water availability in the Levant is predicted to decline due to global warming in the upcoming decades and is expected to substantially impact the region. Determining the long-term natural rainfall variability in this region is essential for understanding the regional hydroclimatic response to external climate forcings and for contex- tualizing future hydroclimate changes. The Dead Sea (DS), located in the southern Levant, is a closed-basin lake whose size varies as a function of water availability. Reconstructing DS lake-level variations through time provides a quantitative measure of the natural hydroclimate variability and can inform on the local hydroclimate response to changes in global climate. Here, we constructed an updated lake-level history of the Holocene DS by: 1) studying lake high-stands derived from a series of new cores collected in the DS southern basin, 2) re-dating of the two major Holocene high-stand exposures, and 3) compiling all previously published ages of Holocene DS lake-level markers (n = 296 radiocarbon ages). The results show that the early (10–6.1 kyr cal BP) and late Holocene (3.6–0 kyr cal BP) in the DS were predominantly wet albeit punctuated by dry intervals, whereas the middle Holocene (6.1–3.6 kyr cal BP) was most likely relatively dry. This pattern of two Holocene humid in- tervals is also evident in distillation records derived from Levant speleothem caves (which represent the inte- grated magnitude of rainout from the vapor source to the caves), indicating that rainfall intensity and total water availability were correlated throughout the Holocene. These two humid intervals occurred during high and low summer insolation conditions, suggesting that they were modulated by different climatic mechanisms. The predicted future drying in the Levant is of similar magnitude to the natural hydroclimate variability and thus, it is crucial to assess whether the anthropogenic drying is in- or out-of phase with the natural climate variability. 

Abstract ²³⁰Th normalization is a valuable paleoceanographic tool for reconstructing high‐resolution sediment fluxes during the late Pleistocene (last ~500,000 years). As its application has expanded to ever more diverse marine environments, the nuances of²³⁰Th systematics, with regard to particle type, particle size, lateral advective/diffusive redistribution, and other processes, have emerged. We synthesized over 1000 sedimentary records of²³⁰Th from across the global ocean at two time slices, the late Holocene (0–5,000 years ago, or 0–5 ka) and the Last Glacial Maximum (18.5–23.5 ka), and investigated the spatial structure of²³⁰Th‐normalized mass fluxes. On a global scale, sedimentary mass fluxes were significantly higher during the Last Glacial Maximum (1.79–2.17 g/cm²kyr, 95% confidence) relative to the Holocene (1.48–1.68 g/cm²kyr, 95% confidence). We then examined the potential confounding influences of boundary scavenging, nepheloid layers, hydrothermal scavenging, size‐dependent sediment fractionation, and carbonate dissolution on the efficacy of²³⁰Th as a constant flux proxy. Anomalous²³⁰Th behavior is sometimes observed proximal to hydrothermal ridges and in continental margins where high particle fluxes and steep continental slopes can lead to the combined effects of boundary scavenging and nepheloid interference. Notwithstanding these limitations, we found that²³⁰Th normalization is a robust tool for determining sediment mass accumulation rates in the majority of pelagic marine settings (>1,000 m water depth).