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California has committed to ambitious decarbonization targets across multiple sectors, including decarbonizing the electrical grid by 2045. In addition, the medium- and heavy-duty truck fleets are expected to see rapid electrification over the next two decades. Considering these two pathways in tandem is critical for ensuring cost optimality and reliable power system operation. In particular, we examine the potential cost savings of electrical generation infrastructure by enabling flexible charging and bidirectional charging for these trucks. We also examine costs adjacent to enabling these services, such as charger upgrades and battery degradation. We deploy a large mixed-integer decarbonization planning model to quantify the costs associated with the electric generation decarbonization pathway. Example scenarios governing truck driving and charging behaviors are implemented to reveal the sensitivity of temporal driving patterns. Our experiments show that cost savings on the order of multiple billions of dollars are possible by enabling flexible and bidirectional charging in medium- and heavy-duty trucks in California. 

We present a novel topology-preserving 3D medial axis computation framework based on volumetric restricted power diagram (RPD), while preserving the medial features and geometric convergence simultaneously, for both 3D CAD and organic shapes. The volumetric RPD discretizes the input 3D volume into sub-regions given a set of medial spheres. With this intermediate structure, we convert the homotopy equivalency between the generated medial mesh and the input 3D shape into a localized contractibility checking for each restricted element (power cell, power face, power edge), by checking their connected components and Euler characteristics. We further propose a fractional Euler characteristic algorithm for efficient GPU-based computation of Euler characteristic for each restricted element on the fly while computing the volumetric RPD. Compared with existing voxel-based or point-cloud-based methods, our approach is the first to adaptively and directly revise the medial mesh without globally modifying the dependent structure, such as voxel size or sampling density, while preserving its topology and medial features. In comparison with the feature preservation method MATFP [Wang et al. 2022], our method provides geometrically comparable results with fewer spheres and more robustly captures the topology of the input 3D shape. 

Atomic force microscopy (AFM), in particular force spectroscopy, is a powerful tool for understanding the supramolecular structures associated with polymers grafted to surfaces, especially in regimes of low polymer density where different morphological structures are expected. In this study, we utilize force volume mapping to characterize the nanoscale surfaces of Ag nanocubes (AgNCs) grafted with a monolayer of polyethylene glycol (PEG) chains. Spatially resolved force−distance curves taken for a single AgNC were used to map surface properties, such as adhesion energy and deformation. We confirm the presence of surface octopus micelles that are localized on the corners of the AgNC, using force curves to resolve structural differences between the micelle “bodies” and “legs”. Furthermore, we observe unique features of this system including a polymer corona stemming from AgNC−substrate interactions and polymer bridging stemming from particle−particle interactions. 

One of the key challenges in separation science is the lack of precise ion separation methods and mechanistic understanding crucial for efficiently recovering critical materials from complex aqueous matrices. Herein, first‐principles electronic structure calculations and in situ Raman spectroscopy are studied to elucidate the factors governing ion discrimination in an adsorptive membrane specifically designed for transition metal ion separation. Density functional theory calculations and in situ Raman data jointly reveal the thermodynamically favorable binding preferences and detailed adsorption mechanisms for competing ions. How membrane binding preferences correlate with the electronic properties of ligands is explored, such as orbital hybridization and electron localization. The findings underscore the importance of the phenolate group in oxime ligands for achieving high selectivity among competing transition metal ions. In‐depth understanding on which specific atomistic site within the microenvironment of metal‐ligand binding pockets governs the ion discrimination behaviors of the host will build a solid foundation to guide the rational design of next‐generation materials for precision separation essential for energy technologies and environment remediation. In tandem, synthetic controllability is demonstrated to transform 3D micrometer‐scale crystals to a 2D crystalline selective layer in membranes, paving the way for more precise and sustainable advances in separation science. 

Humans and other animals can maintain constant payoffs in an uncertain environment by steadily re-evaluating and flexibly adjusting current strategy, which largely depends on the interactions between the prefrontal cortex (PFC) and mediodorsal thalamus (MD). While the ventromedial PFC (vmPFC) represents the level of uncertainty (i.e., prior belief about external states), it remains unclear how the brain recruits the PFC-MD network to re-evaluate decision strategy based on the uncertainty. Here, we leverage non-linear dynamic causal modeling on fMRI data to test how prior belief-dependent activity in vmPFC gates the information flow in the PFC-MD network when individuals switch their decision strategy. We show that the prior belief-related responses in vmPFC had a modulatory influence on the connections from dorsolateral PFC (dlPFC) to both, lateral orbitofrontal (lOFC) and MD. Bayesian parameter averaging revealed that only the connection from the dlPFC to lOFC surpassed the significant threshold, which indicates that the weaker the prior belief, the less was the inhibitory influence of the vmPFC on the strength of effective connections from dlPFC to lOFC. These findings suggest that the vmPFC acts as a gatekeeper for the recruitment of processing resources to re-evaluate the decision strategy in situations of high uncertainty.