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Abstract Color centers in the O-band (1260–1360 nm) are crucial for realizing long-coherence quantum network nodes in memory-assisted quantum communications. However, only a limited number of O-band color centers have been thoroughly explored in silicon hosts as spin-photon interfaces. This study explores and compares two promising O-band color centers in silicon for high-fidelity spin-photon interfaces: T and *Cu (transition metal) centers. During T center generation process, we observed the formation and dissolution of other color centers, including the copper-silver related centers with a doublet line around 1312 nm (*$${{{\rm{Cu}}}}_{n}^{0}$$ ${\mathrm{Cu}}_n^0$), near the optical fiber zero dispersion wavelength (around 1310 nm). We then investigated the photophysics of both T and *Cu centers, focusing on their emission spectra and spin properties. The *$${{{\rm{Cu}}}}_{0}^{0}$$ ${\mathrm{Cu}}_0^0$line under a 0.5 T magnetic field demonstrated a 25% broadening, potentially due to spin degeneracy, suggesting that this center can be a promising alternative to T centers. 

Abstract The advancement of microcomb sources, which serve as a versatile and powerful platform for various time–frequency measurements, have spurred widespread interest across disciplines. Their uses span coherent optical and microwave communications, atomic clocks, high-precision LiDARs, spectrometers, and frequency synthesizers. Recent breakthroughs in fabricating optical micro-cavities, along with the excitation and control of microcombs, have broadened their applications, bridging the gap between physical exploration and practical engineering systems. These developments pave the way for pioneering approaches in both classical and quantum information sciences. In this review article, we conduct a thorough examination of the latest strategies related to microcombs, their enhancement and functionalization schemes, and cutting-edge applications that cover signal generation, data transmission, quantum analysis, and information gathering, processing and computation. Additionally, we provide in-depth evaluations of microcomb-based methodologies tailored for a variety of applications. To conclude, we consider the current state of research and suggest a prospective roadmap that could transition microcomb technology from laboratory settings to broader real-world applications. 

Abstract Dissipative Kerr soliton microcombs in microresonators have enabled fundamental advances in chip-scale precision metrology, communication, spectroscopy, and parallel signal processing. Here we demonstrate polarization-diverse soliton transitions and deterministic switching dynamics of a self-stabilized microcomb in a strongly-coupled dispersion-managed microresonator driven with a single pump laser. The switching dynamics are induced by the differential thermorefractivity between coupled transverse-magnetic and transverse-electric supermodes during the forward-backward pump detunings. The achieved large soliton existence range and deterministic transitions benefit from the switching dynamics, leading to the cross-polarized soliton microcomb formation when driven in the transverse-magnetic supermode of the single resonator. Secondly, we demonstrate two distinct polarization-diverse soliton formation routes – arising from chaotic or periodically-modulated waveforms via pump power selection. Thirdly, to observe the cross-polarized supermode transition dynamics, we develop a parametric temporal magnifier with picosecond resolution, MHz frame rate and sub-ns temporal windows. We construct picosecond temporal transition portraits in 100-ns recording length of the strongly-coupled solitons, mapping the transitions from multiple soliton molecular states to singlet solitons. This study underpins polarization-diverse soliton microcombs for chip-scale ultrashort pulse generation, supporting applications in frequency and precision metrology, communications, spectroscopy and information processing.