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Fluorotelomer carboxylic acids (FTCAs) represent an important group of per- and polyfluoroalkyl substances (PFAS) given their high toxicity, bioaccumulation potential, and frequent detection in landfill leachates and PFAS-impacted sites. In this study, we assessed the biodegradability of 6:2 FTCA and 5:3 FTCA by activated sludges from four municipal wastewater treatment plants (WWTPs) in the New York Metropolitan area. Coupling with 6:2 FTCA removal, significant fluoride release (0.56∼1.83 F-/molecule) was evident in sludge treatments during 7 days of incubation. Less-fluorinated transformation products (TPs) were formed, including 6:2 fluorotelomer unsaturated carboxylic acid (6:2 FTUCA), perfluorohexanoic acid (PFHxA), perfluoropentanoic acid (PFPeA), and perfluorobutanoic acid (PFBA). In contrast, little fluoride (0.01∼0.09 F-/molecule) was detected in 5:3 FTCA-dosed microcosms, though 25∼68% of initially dosed 5:3 FTCA was biologically removed. This implies the dominance of “non-fluoride-releasing pathways” that may contribute to the formation of CoA adducts or other conjugates over 5:3 FTCA biotransformation. The discovery of defluorinated 5:3 FTUCA revealed the possibility of microbial attacks of the C-F bond at the γ carbon to initiate the transformation. Microbial community analysis revealed the possible involvement of 9 genera, such as Hyphomicrobium and Dechloromonas, in aerobic FTCA biotransformation. This study unraveled that biotransformation pathways of 6:2 and 5:3 FTCAs can be divergent, resulting in biodefluorination at distinctive degrees. Further research is underscored to uncover the nontarget TPs and investigate the involved biotransformation and biodefluorination mechanisms and molecular basis. 

Suture zones located across the Tibetan region clearly demarcate the rift-and-drift and continental accretion history of the region. However, the intraplate responses to these marginal plate-tectonic events are rarely quantified. Our understanding of the Paleo-Tethyan orogenic system, which involved ocean opening and closing events to grow the central Asian continent, depends on the tectonic architecture and histories of major late Paleozoic−early Mesozoic orogenic belts. These opening and collision events were associated with coupled intracontinental deformation, which has been difficult to resolve due to subsequent overprinting deformation. The late Paleozoic−early Mesozoic Zongwulong Shan−Qinghai Nanshan belt in northern Tibet separates the Qilian and North Qaidam regions and is composed of Carboniferous−Triassic sedimentary materials and mantle-derived magmatic rocks. The tectonic setting and evolutional history of this belt provide important insight into the paleogeographic and tectonic relationships of the Paleo-Tethyan orogenic system located ∼200 km to the south. In this study, we integrated new and previous geological observations, detailed structural mapping, and zircon U-Pb geochronology data from the Zongwulong Shan−Qinghai Nanshan to document a complete tectonic inversion cycle from intraplate rifting to intracontinental shortening associated with the opening and closing of the Paleo-Tethyan Ocean. Carboniferous−Permian strata in the Zongwulong Shan were deposited in an intracontinental rift basin and sourced from both the north and the south. At the end of the Early−Middle Triassic, foreland molasse strata were deposited in the southern part of the Zongwulong Shan during tectonic inversion in the western part of the tectonic belt following the onset of regional contraction deformation. The Zongwulong Shan−Qinghai Nanshan system has experienced polyphase deformation since the late Paleozoic, including: (1) early Carboniferous intracontinental extension and (2) Early−Middle Triassic tectonic inversion involving reactivation of older normal faults as thrusts and folding of pre- and synrift strata. We interpret that the Zongwulong Shan−Qinghai Nanshan initiated as a Carboniferous−Early Triassic intracontinental rift basin related to the opening of the Paleo-Tethyan Ocean to the south, and it was then inverted during the Early−Middle Triassic closing of the Paleo-Tethyan Ocean. This work emphasizes that pre-Cenozoic intraplate structures related to the opening and closing of ocean basins in the Tethyan realm may be underappreciated across Tibet. 

The northwest-trending Altai Mountains of central Asia expose a complex network of thrust and strike-slip faults that are key features accommodating intracontinental crustal shortening related to the Cenozoic India-Asia collision. In this study, we investigated the Quaternary slip history of the Fuyun fault, a right-lateral strike-slip fault bounding the southwestern margin of the Altai Mountains, through geologic mapping, geomorphic surveying, and optically stimulated luminescence (OSL) geochronology. At the Kuoyibagaer site, the Fuyun fault displaces three generations of Pleistocene–Holocene fill-cut river terraces (i.e., T3, T2, and T1) containing landslide and debris-flow deposits. The right-lateral offsets are magnified by erosion of terrace risers, suggesting that river course migration has been faster than slip along the Fuyun fault. The highest Tp2 terrace was abandoned in the middle Pleistocene (150.4 ± 8.1 ka uppermost OSL age) and was displaced 145.5 +45.6/–12.1 m along the Fuyun fault, yielding a slip rate of 1.0 +0.4/–0.1 mm/yr since the middle Pleistocene. The lower Tp1 terrace was abandoned in the late Pleistocene and aggraded by landslides and debris flows in the latest Pleistocene–Holocene (36.7 ± 1.6 ka uppermost OSL age). Tp1 was displaced 67.5 +14.2/–6.1 m along the Fuyun fault, yielding a slip rate of 1.8 +0.5/–0.2 mm/yr since the late Pleistocene. Our preferred minimum slip rate of ~1 mm/yr suggests the Fuyun fault accommodates ~16% of the average geodetic velocity of ~6 mm/yr across the Altai Mountains. Integration of our new Fuyun slip rate with other published fault slip rates accounts for ~4.2 mm/yr of convergence across the Chinese Altai, or ~70% of the geodetic velocity field.

 

The construction of Earth’s largest highland, the Tibetan Plateau, is generally considered to have been generated by the Cenozoic India-Asia collision. However, the extent to which high topography existed prior to the Cenozoic remains unclear. The Hexi Corridor foreland basin of the northern Tibetan Plateau is an ideal region in which to investigate this history, given its widespread exposure of Early Cretaceous sedimentary sequences. In this study, we examined the Early Cretaceous strata in the northern Hexi Corridor to understand the relationships between pre-Cenozoic sedimentation and tectonic deformation and constrain the late Mesozoic tectonic setting of the adjacent Qilian Shan and Alxa blocks bordering the northern Tibetan Plateau. Results of sandstone petrology analyses, paleocurrent observations, and U-Pb geochronology suggest that the oldest Early Cretaceous sediments deposited in the northern Hexi Corridor were sourced from the southern Alxa block during the earliest Cretaceous. By the late Early Cretaceous, Hexi Corridor sediments were sourced from both the southern Alxa block to the north and the Qilian Shan to the south. Sandstone petrologic results indicate that the northern Hexi Corridor experienced a tectonic transition from contraction to extension during the Early Cretaceous. These findings suggest that the northern Tibetan Plateau region was partially uplifted to a high elevation during the late Mesozoic before the India-Asia collision. 

Eclogite bodies exposed across Tibet record a history of subduction-collision events that preceded growth of the Tibetan Plateau. Deciphering the time-space patterns of eclogite generation improves our knowledge of the preconditions for Cenozoic orogeny in Tibet and broader eclogite formation and/or exhumation processes. Here we report the discovery of Permo-Triassic eclogite in northern Tibet. U-Pb zircon dating and thermobarometry suggest eclogite-facies metamorphism at ca. 262–240 Ma at peak pressures of ∼2.5 GPa. Inherited zircons and geochemistry show the eclogite was derived from an upper-plate continental protolith, which must have experienced subduction erosion to transport the protolith mafic bodies to eclogite-forming conditions. The Dabie eclogites to the east experienced a similar history, and we interpret that these two coeval eclogite exposures formed by subduction erosion of the upper plate and deep trench burial along the same ∼3000-km-long north-dipping Permo-Triassic subduction complex. We interpret the synchroneity of eclogitization along the strike length of the subduction zone to have been driven by accelerated plate convergence due to ca. 260 Ma Emeishan plume impingement. 

The occurrence of plate tectonic processes on Earth during the Paleoproterozoic is supported by ca. 2.2–1.8 Ga subduction‐collision orogens associated with the assembly of the Columbia‐Nuna supercontinent. Subsequent supercontinent breakup is evidence by global ca. 1.8–1.6 Ga large igneous provinces. The North China craton is notable for containing Paleoproterozoic orogens along its margins, herein named the Northern Margin orogen, yet the nature and timing of orogenic and extensional processes of these orogens and their role in the supercontinent cycle remain unclear. In this contribution, we present new field observations, U‐Pb zircon and baddeleyite geochronology dates, and major/trace‐element and isotope geochemical analyses from the northern margin of the North China craton that detail its Paleoproterozoic tectonic and magmatic history. Specifically, we record the occurrence of ca. 2.2–2.0 Ga magmatic arc rocks, ca. 1.9–1.88 Ga tectonic mélange and mylonitic shear zones, and folded lower Paleoproterozoic strata. These rocks were affected by ca. 1.9–1.8 Ga granulite‐facies metamorphism and ca. 1.87–1.78 Ga post‐collisional, extension‐related magmatism along the cratonal northern margin. We interpret that the generation and emplacement of these rocks, and the coupled metamorphic and magmatic processes, were related to oceanic subduction and subsequent continent‐continent collision during the Paleoproterozoic. The occurrence of ca. 1.77–1.73 Ga mafic dykes and ca. 1.75 Ga mylonitic shear zones along the northern margin of the North China craton may have been related to a regional mantle plume event. Our results are consistent with modern style plate tectonics, including oceanic subduction‐related plate convergence and continent‐continent collision, operating in the Paleoproterozoic.

 

Abstract High-pressure metamorphic rocks occur as distinct belts along subduction zones and collisional orogens or as isolated blocks within orogens or mélanges and represent continental materials that were subducted to deep depths and subsequently exhumed to the shallow crust. Understanding the burial and exhumation processes and the sizes and shapes of the high-pressure blocks is important for providing insight into global geodynamics and plate tectonic processes. The South Beishan orogen of northwestern China is notable for the exposure of early Paleozoic high-pressure (HP), eclogite-facies metamorphic rocks, yet the tectonism associated with the HP metamorphism and mechanism of exhumation are poorly understood despite being key to understanding the tectonic evolution of the larger Central Asian Orogenic System. To address this issue, we examined the geometries, kinematics, and overprinting relationships of structures and determined the temperatures and timings of deformation and metamorphism of the HP rocks of the South Beishan orogen. Geochronological results show that the South Beishan orogen contains ca. 1.55–1.35 Ga basement metamorphic rocks and ca. 970–866 Ma granitoids generated during a regional tectono-magmatic event. Ca. 500–450 Ma crustal thickening and HP metamorphism may have been related to regional contraction in the South Beishan orogen. Ca. 900–800 Ma protoliths experienced eclogite-facies metamorphism (~1.2–2.1 GPa and ~700–800 °C) in thickened lower crust. These HP rocks were subsequently exhumed after ca. 450 Ma to mid-crustal depths in the footwall of a regional detachment fault during southeast-northwest–oriented crustal extension, possibly as the result of rollback of a subducted oceanic slab. Prior to ca. 438 Ma, north-south–oriented contraction resulted in isoclinal folding of the detachment fault and HP rocks. Following this contractional phase in the middle Mesozoic, the South Beishan orogen experienced thrusting interpreted to be the response to the closure of the Tethyan and Paleo-Asian Ocean domains. This contractional phase was followed by late Mesozoic extension and subsequent surface erosion that controlled exhumation of the HP rocks. 

The Beishan orogen is part of the Neoproterozoic to early Mesozoic Central Asian Orogenic System in central Asia that exposes ophiolitic complexes, passive-margin strata, arc assemblages, and Precambrian basement rocks. To better constrain the tectonic evolution of the Beishan orogen, we conducted field mapping, U-Pb zircon dating, whole-rock geochemical analysis, and Sr-Nd isotopic analysis. The new results, when interpreted in the context of the known geological setting, show that the Beishan region had experienced five phases of arc magmatism at ca. 1450−1395 Ma, ca. 1071−867 Ma, ca. 542−395 Ma, ca. 468−212 Ma, and ca. 307−212 Ma. In order to explain the geological, geochemical, and geochronological data from the Beishan region, we present a tectonic model that involves the following five phases of deformation: (1) Proterozoic rifting that separated the North Beishan block from the Greater North China craton that led to the opening of the Beishan Ocean, (2) early Paleozoic north-dipping subduction (ca. 530−430 Ma) of the Beishan oceanic plate associated with back-arc extension followed by collision between the North and South Beishan microcontinental blocks, (3) northward slab rollback of the south-dipping subducting Paleo-Asian oceanic plate at ca. 450−440 Ma along the northern margin of the North Beishan block that led to the formation of a northward-younging extensional continental arc (ca. 470−280 Ma) associated with bimodal igneous activity, which indicates that the westward extension of the Solonker suture is located north of the Hongshishan-Pengboshan tectonic zone, (4) Late Carboniferous opening and Permian north-dipping subduction of the Liuyuan Ocean in the southern Beishan orogen, and (5) Mesozoic-Cenozoic intracontinental deformation induced by the final closure of the Paleo-Asian Ocean system in the north and the Tethyan Ocean system in the south.