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The quasi-two-dimensional kagome materials AV3Sb5 (A = K, Rb, Cs) were found to be a prime example of kagome superconductors, a new quantum platform to investigate the interplay between electron correlation effects, topology and geometric frustration. In this review, we report recent progress on the experimental and theoretical studies of AV3Sb5 and provide a broad picture of this fast-developing field in order to stimulate an expanded search for unconventional kagome superconductors. We review the electronic properties of AV3Sb5, the experimental measurements of the charge density wave state, evidence of time-reversal symmetry breaking and other potential hidden symmetry breaking in these materials. A variety of theoretical proposals and models that address the nature of the time-reversal symmetry breaking are discussed. Finally, we review the superconducting properties of AV3Sb5, especially the potential pairing symmetries and the interplay between superconductivity and the charge density wave state.

Abstract In high-temperature ( T c ) cuprate superconductors, many exotic phenomena are rooted in the enigmatic pseudogap state, which has been interpreted as consisting of preformed Cooper pairs or competing orders or a combination thereof. Observation of pseudogap phenomenologically in electron-doped Sr 2 IrO 4 —the 5d electron counterpart of the cuprates, has spurred intense interest in the strontium iridates as a testbed for exploring the exotic physics of the cuprates. Here, we examine the pseudogap state of electron-doped Sr 2 IrO 4 by angle-resolved photoemission spectroscopy (ARPES) and parallel theoretical modeling. Our analysis demonstrates that the pseudogap state of Sr 2 IrO 4 appears without breaking the particle–hole symmetry or inducing spectral broadening which are telltale signatures of competing orders in the cuprates. We find quasiparticle dispersion and its temperature dependence in the pseudogap state of Sr 2 IrO 4 to point to an electronic order with a zero scattering wave vector and limited correlation length. Particle–hole symmetric preformed Cooper pairs are discussed as a viable mechanism for such an electronic order. The potential roles of incommensurate density waves are also discussed.

The Transiting Exoplanet Survey Satellite (TESS) mission searches for new exoplanets. The observing strategy of TESS results in high-precision photometry of millions of stars across the sky, allowing for detailed asteroseismic studies of individual systems. In this work, we present a detailed asteroseismic analysis of the giant star HD 76920 hosting a highly eccentric giant planet (e= 0.878) with an orbital period of 415 days, using five sectors of TESS light curve that cover around 140 days of data. Solar-like oscillations in HD 76920 are detected around 52μHz by TESS for the first time. By utilizing asteroseismic modeling that takes classical observational parameters and stellar oscillation frequencies as constraints, we determine improved measurements of the stellar mass (1.22 ± 0.11M_⊙), radius (8.68 ± 0.34R_☉), and age (5.2 ± 1.4 Gyr). With the updated parameters of the host star, we update the semimajor axis and mass of the planet asa= 1.165 ± 0.035 au and$M_{\mathrm{p}}\sin i=3.57\pm 0.22M_{\mathrm{Jup}}$. With an orbital pericenter of 0.142 ± 0.005 au, we confirm that the planet is currently far away enough from the star to experience negligible tidal decay until being engulfed in the stellar envelope. We also confirm that this eventmore »will occur within about 100 Myr, depending on the stellar model used.

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Zeolites (ZSM-5 and Beta) with different SiO2/Al2O3 ratios were synthesized as solid acids for hydrolyzing cellulose in an inorganic ionic liquid system (lithium bromide trihydrate solution, LBTH) under mild conditions. The results indicated that the texture properties of zeolite had little effect on catalytic activity, while acidity of zeolite was crucial to the cellulose hydrolysis. In the LBTH system, H-form zeolites released H+ into the solution from their acid sites via ion-exchange with Li+, which hydrolyzed the cellulose already dissolved. This unique homogeneous hydrolysis mechanism was the primary reason for the excellent performance of the zeolites in catalyzing cellulose hydrolysis in the LBTH system. It was found cellulose could be completely hydrolyzed to glucose and oligoglucan by 2% (w/w on cellulose) zeolite at 140 °C within 3 h with a single-pass glucose yield 61%. The zeolites could be recovered with 50% initial catalytic activity after regeneration and reused with stable catalytic activity.