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BSTRACT:Piezoelectricmaterialsare used to fabricateacoustictransducersforbubblechambersin searchfor particlesof dark matter.It has been shownthat bubblesinitiatedby nuclearrecoilsemit acousticradiationdistinguishablefrom the phasetransitionscausedby alpha-decay�themain backgroundnoisein such searches.However,these piezoelectricmaterialsmust exhibitultralowradioactivityto minimizethe neutronbackgroundfor dark matterdetectionwhilepossessinghigh acousticsensitivity.Here,for the first time, we demonstrateradiopurehigh-performancepiezoelectricceramicsmeetingthe criteriafor acousticsensing.The screeningofradiopureprecursorsis performedto identifythose with low238U,232Th, and210Pbcontents.Usingthe radiopureprecursors,piezoelectricceramicswith varyingcompositionsare synthesized,and their electromechanicalacousticsensingperformanceis evaluated.Multiplesynthesismodificationssuch as dopingand texturingare utilizedtotailor the piezoelectriccoefficientsof the piezoelectricceramics,and the relationshipbetweenthe piezoelectriccoefficientsand acousticsensingperformanceof the ceramicsis investigated.Acoustictransducersfabricatedusing texturedPb(Mg1/3Nb2/3)O3−PbTiO3(PMN−PT)ceramicsare found to exhibitsuperioracousticsensitivitydue totheir high piezoelectrictransductioncoefficient(d33×g33). This study demonstratesa usefulfigure of merit (FOM)for acousticsensingin bubblechambers 

Abstract Piezoelectric materials enable the conversion of mechanical energy into electrical energy and vice‐versa. Ultrahigh piezoelectricity has been only observed in single crystals. Realization of piezoelectric ceramics with longitudinal piezoelectric constant (d₃₃) close to 2000 pC N^–1, which combines single crystal‐like high properties and ceramic‐like cost effectiveness, large‐scale manufacturing, and machinability will be a milestone in advancement of piezoelectric ceramic materials. Here, guided by phenomenological models and phase‐field simulations that provide conditions for flattening the energy landscape of polarization, a synergistic design strategy is demonstrated that exploits compositionally driven local structural heterogeneity and microstructural grain orientation/texturing to provide record piezoelectricity in ceramics. This strategy is demonstrated on [001]_PC‐textured and Eu³⁺‐doped Pb(Mg_1/3Nb_2/3)O₃‐PbTiO₃(PMN‐PT) ceramics that exhibit the highest piezoelectric coefficient (small‐signald₃₃of up to 1950 pC N^–1and large‐signald₃₃* of ≈2100 pm V^–1) among all the reported piezoelectric ceramics. Extensive characterization conducted using high‐resolution microscopy and diffraction techniques in conjunction with the computational models reveals the underlying mechanisms governing the piezoelectric performance. Further, the impact of losses on the electromechanical coupling is identified, which plays major role in suppressing the percentage of piezoelectricity enhancement, and the fundamental understanding of loss in this study sheds light on further enhancement of piezoelectricity. These results on cost‐effective and record performance piezoelectric ceramics will launch a new generation of piezoelectric applications. 

Abstract Relaxor ferroelectrics (RFEs) are being actively investigated for energy‐storage applications due to their large electric‐field‐induced polarization with slim hysteresis and fast energy charging–discharging capability. Here, a novel nanograin engineering approach based upon high kinetic energy deposition is reported, for mechanically inducing the RFE behavior in a normal ferroelectric Pb(Zr_0.52Ti_0.48)O₃(PZT), which results in simultaneous enhancement in the dielectric breakdown strength (E_DBS) and polarization. Mechanically transformed relaxor thick films with 4 µm thickness exhibit an exceptionalE_DBSof 540 MV m⁻¹and reduced hysteresis with large unsaturated polarization (103.6 µC cm⁻²), resulting in a record high energy‐storage density of 124.1 J cm⁻³and a power density of 64.5 MW cm⁻³. This fundamental advancement is correlated with the generalized nanostructure design that comprises nanocrystalline phases embedded within the amorphous matrix. Microstructure‐tailored ferroelectric behavior overcomes the limitations imposed by traditional compositional design methods and provides a feasible pathway for realization of high‐performance energy‐storage materials.