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Electrowetting and wettability-driven spreading of liquids on porous and nonporous substrates was investigated using impact of drops of epoxy resin, epoxy hardener, and epoxy resin and hardener, as well as silicone and turpentine oils with oil-soluble aniline dyes onto balsa wood and polypropylene surfaces. The experimental results revealed that the electric field stretched drops of epoxy resin, epoxy hardener, and epoxy resin and hardener after impact on polypropylene substrate in the long-term. The spreading of drops of epoxy resin and turpentine oil with dyes after impact onto porous balsa wood under the action of a 10 kV applied voltage was relatively weak. In addition, the measured footprint areas corresponding to drops of epoxy resin, epoxy hardener, and epoxy resin and hardener demonstrated a significant increase in the wetted areas driven by the applied voltage of 10 kV on polypropylene substrate, whereas on balsa wood, the footprint is practically unaffected by the electric field. Furthermore, it was determined that surface wettability was the main mechanism of spreading of epoxy resin, as well as silicone and turpentine oils with aniline dyes on porous balsa without the electric field applied. On the other hand, insufficient concentration of ions and counterions in silicone oil was responsible for the absence of electrohydrodynamic effects after impact of such drops onto porous balsa substrate subjected to high potentials of 7 and 10 kV. Hence, wettability-driven spreading with imbibition on balsa wood was the only reason for an increase in the wetted area in the case of silicone oil. 

Green synthesis of micro/nanomaterials, using glycerol as a sustainable solvent, offers environmentally and health-friendly pathways. Glycerol’s versatility in a solvothermal synthesis is effective for nanoparticle production, yet its mechanistic role in carbonate material formation is unexplored. This study investigates urchin-like strontium carbonate formation via a glycerol-mediated solvothermal synthesis, employing in situ transmission electron microscopy (in situ TEM), scanning electron microscopy, density function theory (DFT), scanning transmission electron microscopy, and X-ray diffraction. In situ TEM observations unveil the initial stages of strontium hydroxide nucleation and subsequent growth as an intermediate phase. The findings suggested that the hyperbranched polymerization of glycerol plays a pivotal role in the formation of urchin-like morphology. Furthermore, the synergistic effect of glycerol and CO2 is proposed as the primary driver for the formation of strontium carbonate. Notably, observations showed a morphological transition from spherical to urchin-like with increasing reaction time. DFT studies proposed glycerol as a coadsorbent, boosting the adsorption energy of CO2 and directing its interaction with Sr(OH)2 resulting in the stable formation of SrCO3. This research provides valuable insights into the urchin-like strontium carbonate formation in a time-dependent process driven by the polymerization of glycerol and its high reactivity with dissolved CO2 at elevated temperatures. 

Dendritic growth of lithium (Li) is hindering potential applications of Li-metal batteries, and new approaches are needed to address this challenge. The confinement effect of two-dimensional materials triggered by strong molecular interactions between parallelly-aligned graphene oxide (GO) at Li metal interface is proposed here as a new strategy to suppress the dendritic growth of Li. The effectiveness of aligned GO for Li-metal cells is shown for two different polymer separator cells:liquid electrolytes with porous propylene (PP) separators and solid polyethylene oxide (PEO) electrolytes. For the case of liquid electrolytes, PP separators were modified with plasma treatment to induce the alignment of GO layers. The Li‖Li cells with aligned GO illustrate a stable Li platting/stripping (up to 1000 cycles). The Li‖lithium iron phosphate (LFP) battery cells with aligned GO could cycle at 5C for 1000 cycles (∼90% capacity retention). For solid polymer electrolyte (SPE) cells, GO–Li confinement effect is also effective in Li dendrites suppression enhancing the stability and lifespan of Li-metal batteries. The Li‖LFP cell with the GO-modified SPE showed ∼85% capacity retention after 200 cycles at 1C. Such combined high rate capability and number of cycles exceeds the previously reported performances for both liquid and SPE-based Li‖LFP cells. This points to a new opportunity for utilizing the confinement effect of two-dimensional materials for the development of next generation, fast rate rechargeable Li batteries. 

Experimental observations of drops of water with aniline dye softly located or impacting onto balsa wood substrates were used to elucidate the effect of an in-plane electric field (at a high voltage of 10 kV applied) on drop behavior. The top and side views were recorded simultaneously. The short-term recordings (on the scale of a few ms) demonstrated a slight effect of the applied in-plane electric field. In some trials, a greater number of finger-like structures were observed along the drop rim compared to the trials without voltage applied. These fingers developed during the advancing motion of the drop rim. The long-term recording (on the scale of ∼10 s) was used to evaluate the wettability-driven increase in the area-equivalent radius of the wetted area. These substrates had grooves in the inter-electrode or the cross-field directions. The groove directions affected the wettability-driven spreading and imbibition. The wettability-driven spreading in the long term was a much more significant effect than the effect of the electric field, because the imbibition significantly diminished the drop part above the porous surface, which diminished, in turn, the electric Maxwell stresses, which could stretch the drop. A simplified analytical model was developed to measure the moisture transport coefficient responsible for liquid imbibition in these experiments. Furthermore, the phase-field modeling of drops on balsa was used to illustrate how a change in the contact angle from hydrophobic to hydrophilic triggers drop imbibition into balsa wood.