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Testing the Limits of Imbalanced CPET Reactivity: Mechanistic Crossover in H-Atom Abstraction by Co(III)–Oxo Complexes

https://doi.org/10.1021/jacs.2c10553

Zhao, Norman; Goetz, McKenna K.; Schneider, Joseph E.; Anderson, John S. (March 2023, Journal of the American Chemical Society)

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Intrinsic glassy-metallic transport in an amorphous coordination polymer

https://doi.org/10.1038/s41586-022-05261-4

Xie, Jiaze; Ewing, Simon; Boyn, Jan-Niklas; Filatov, Alexander S.; Cheng, Baorui; Ma, Tengzhou; Grocke, Garrett L.; Zhao, Norman; Itani, Ram; Sun, Xiaotong; et al (November 2022, Nature)

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Generation and Reactivity of a Ni ^III ₂ (μ-1,2-peroxo) Complex

https://doi.org/10.1021/jacs.0c10958

Zhao, Norman; Filatov, Alexander S.; Xie, Jiaze; Hill, Ethan A.; Rogachev, Andrey Yu.; Anderson, John S. (December 2020, Journal of the American Chemical Society)
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Nickel( ii )-methyl complexes adopting unusual seesaw geometries

https://doi.org/10.1039/C9CC09249H

Hill, Ethan A.; Zhao, Norman; Filatov, Alexander S.; Anderson, John S. (January 2020, Chemical Communications)

We report four-coordinate nickel( ii )-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.
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