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Title: Nickel( ii )-methyl complexes adopting unusual seesaw geometries
We report four-coordinate nickel( ii )-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.  more » « less
Award ID(s):
1654144 1834750
NSF-PAR ID:
10167956
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Chemical Communications
ISSN:
1359-7345
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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