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Ferroelectrics with multifunctionalities are gaining increased interest in self-actuated electrocaloric effect (ECE) refrigerators. However, achieving high ECE and electromechanical (EM) coupling concomitantly for maximum heat transfer remains challenging. Here we present the structure-property relationship for poly(vinylidene fluoride-co-trifluoroethylene-co-chlorofluoroethylene-co-double bond), P(VDF-TrFE-CFE-DB), tetrapolymer, which exhibited a high ECE entropy change of 66.5 J·Kg⁻¹·K⁻¹ and EM strain of -6.1%. We show that thermal treatment can be a key factor influencing multifunctional properties. High-temperature annealing incorporates DB and CFE units into crystalline grains to form extended-chain crystals, enabling CFE units to induce relaxor behavior and DB units to induce large structural changes at low electric fields. This synergy leads to an enhancement in both ECE and EM performances. Furthermore, at an optimized temperature of 50°C, the annealed films exhibit giant cross-energy coupling, achieving ECE and EM performances of 100.8 J·Kg⁻¹·K⁻¹ and -7.6%. This study provides insights into developing new ferroelectric polymers with electroactive multifunctionalities. 

Relaxor ferroelectric (RFE) polymers hold great promise for artificial muscles due to their high actuation strain, high loading stress, and fast response. However, the structural origin underlying their large electrostrictive deformation remains elusive. In this study, we investigate poly(vinylidene fluoride-co-trifluoroethylene) [P(VDF-TrFE)]-based RFE terpolymers, incorporating 1,1-chlorofluoroethylene (CFE) or chlorotrifluoroethylene (CTFE) (the terpolymers are denoted as terP-CFE and terP-CTFE, respectively) as termonomers. Although both terpolymers show similar semicrystalline morphology, drastically different electrostrictive properties are observed. Specifically, the terP-CFE annealed at 100 °C achieves a record-high transverse strain of ~10.6%, whereas 100 °C-annealed terP-CTFE only shows a much lower actuation strain of ~4.2% at the same poling field of 190 MV/m. To elucidate the origin of this difference, time-resolved wide-angle X-ray diffraction, small-angle X-ray scattering, and Fourier transform infrared experiments are performed during in-situ electric poling. An RFE-to-ferroelectric (FE) crystal phase transition is observed for terP-CFE, but is absent for terP-CTFE. Beyond the contribution of the crystalline phase, the oriented amorphous fraction and crystalline defects (e.g., taut-tie molecules) also play significant roles in enhancing electrostriction. This mechanistic insight provides a valuable foundation for the rational design of next-generation RFE polymers with tunable properties through defect-engineering of their semicrystalline structures. 

A dynamic view of mass assembly is essential for understanding the formation of massive stars and clusters. However, interpreting evolutionary diagnostics from Galactic-wide surveys requires careful consideration of distance and environmental variations. The G316.8 filament provides an excellent controlled case: a 14-parsec, nearly linear structure comprising three contiguous subregions with comparable molecular gas reservoirs (each ~10 000M_⊙), yet spanning a clear evolutionary sequence from a northern infrared dark cloud (young) through a central massive young stellar object (intermediate), to a southern HIIregion (evolved). TheLinear filament and nested cluster evolution tomography(LANCET) project mapped the entire G316.8 filament with the Atacama Compact Array (ACA) at 1.3 mm, achieving 6″ (0.08 pc) resolution over 26.7 arcmin²(17.1 pc²). By combining ACA 7 m data withHerscheland APEX/ArTéMiS observations, we produced high-resolution temperature and column-density maps. We quantified subregional differences using (i) dense-fragment statistics, (ii) column-density probability distribution functions (N-PDFs), and (iii) the scale-dependent structural diagnostic, the Δ-variance. From young to intermediate to evolved, the maximum fragment mass increases from 8 to 160 to 490M_⊙, while the dense-gas mass fraction (>0.5 g cm⁻²) rises from 0.4 to 2.3 to 9.6%. Along this sequence, the N-PDF develops a slightly flatter primary power-law tail and an additional, steeper secondary tail; the Δ-variance slope becomes progressively shallower. Across G316.8, the subregional differences consistently indicate a coherent evolutionary trend of massive star formation, in which gas is continuously assembled into sub-parsec dense structures. The forthcoming 12 m array observations are about to extend this dynamic picture by resolving dense core formation and probing gas kinematics and magnetic fields. 

Within the linear regime of mechanical and electrical responses, it is commonly accepted that direct and converse piezoelectric coefficients should be the same. However, we observed a consistently higher converse d31 (∼54 pm/V) than the direct d31 (∼42 pC/N) for a quenched, stretched, annealed, and electrically poled poly(vinylidene fluoride-co-trifluorethylene) [P(VDF-TrFE)] 52/48 mol.% sample (abbreviated as coP-52/48QSAP). On the contrary, the direct and converse d31 values were the same for coP-65/35QSAP and coP-55/45QSAP. Small-angle X-ray scattering results showed that coP-52/48QSAP had a higher amount of relaxor-like secondary crystals (SCs) in the oriented amorphous fraction (OAF) (SCOAF) than coP-55/45QSAP and coP-65/35QSAP. To explain the experimental observation, we performed molecular dynamics (MD) simulation of the pure PVDF (without TrFE) to estimate direct and converse piezoelectricity for the PVDF OAF. Based on the MD simulation, the direct d31 had a plateau value around 350 pC/N for the transverse (i.e., along the chain direction) strain up to 1 %, whereas the simulated converse d31 could be lower (for electric field E < 0.8 MV/m), equal (for E = 0.8 MV/m), or higher (for E > 0.8 MV/m) than the direct d31, depending on the poling electric field. From the MD simulation, both mechano-electrostriction and electrostatic interaction were identified in the OAF as the driving force for enhanced piezoelectricity in ferroelectric PVDF. When ferroelectric domains were formed in the OAF by electric poling, the simulated converse d31 became higher than the direct d31. Combining both experimental and MD simulation results, the higher converse d31 than direct d31 for coP-52/48QSAP was understood qualitatively. 

An ansa-neodymocene catalyst was identified to catalyze the titled copolymerization to afford isoprene-ethylene rubber (IER) with 95% selectivity for the 1,4-trans-isoprene-ethylene microstructure. The 95% structural regularity is required for IER to exhibit prominent strain-induced crystallization (SIC). The mechanical property of IER rivals that of natural rubber at 0 °C, at which temperature SIC occurs for both. The unit cell of the strain-induced crystals is monoclinic with a = 2.21 nm, b = 0.72 nm, c = 1.30 nm, and β = 110.8°. Each unit cell is estimated to contain 12 chains in the ac plane and one repeat unit along the b axis. 

The decay of methyl chloroform, a banned ozone-depleting substance, has provided a clear observational metric of mean tropospheric hydroxyl radical (OH) abundance. Almost all current global chemistry models calculate about 15% too much OH and thus too rapid methane loss. Methane is a short-lived climate forcer, critical to achieving global warming targets, and this error affects our model projections of climate change. New observations of water vapor absorption in the ultraviolet region (290 to 350 nanometers) imply reductions in sunlight with key photolysis rates decreasing by 8 to 12% in the near-surface tropical atmosphere. Incorporation of this new mechanism in a chemistry-transport model reduces OH and methane loss by only 4%, but combined with other proposed mechanisms, such as tropospheric halogen chemistry (7%), we may be able to resolve this conundrum.