- Home
- Search Results
- Page 1 of 1
Search for: All records
-
Total Resources3
- Resource Type
-
00030
- Availability
-
21
- Author / Contributor
- Filter by Author / Creator
-
-
Makris, Thomas M. (3)
-
Manley, Olivia M. (3)
-
Amaya, Jose A. (1)
-
Dutra, Matthew (1)
-
Garashchuk, Sophya (1)
-
Islam, Mohammad Jahirul (1)
-
Ma, Dumei (1)
-
McElhenney, Shannon (1)
-
Park, Kyoung Chul (1)
-
Peryshkov, Dmitry V. (1)
-
Rassolov, Vitaly (1)
-
Smith, Mark D. (1)
-
Wang, Qian (1)
-
Yin, Yingwu (1)
-
Zhang, Libo (1)
-
#Tyler Phillips, Kenneth E. (0)
-
#Willis, Ciara (0)
-
& Abreu-Ramos, E. D. (0)
-
& Abramson, C. I. (0)
-
& Abreu-Ramos, E. D. (0)
-
- Filter by Editor
-
-
& Spizer, S. M. (0)
-
& . Spizer, S. (0)
-
& Ahn, J. (0)
-
& Bateiha, S. (0)
-
& Bosch, N. (0)
-
& Brennan K. (0)
-
& Brennan, K. (0)
-
& Chen, B. (0)
-
& Chen, Bodong (0)
-
& Drown, S. (0)
-
& Ferretti, F. (0)
-
& Higgins, A. (0)
-
& J. Peters (0)
-
& Kali, Y. (0)
-
& Ruiz-Arias, P.M. (0)
-
& S. Spitzer (0)
-
& Spitzer, S. (0)
-
& Spitzer, S.M. (0)
-
(submitted - in Review for IEEE ICASSP-2024) (0)
-
- (0)
-
-
Have feedback or suggestions for a way to improve these results?
!
Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher.
Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?
Some links on this page may take you to non-federal websites. Their policies may differ from this site.
-
We report the synthesis and characterization of a nickel(II) complex of the dicarboranyl CNC dianionic pincer ligand, which activates acetonitrile by C–C bond cleavage. Deprotonation of the relatively acidic C–H bond of the coordinated acetonitrile with potassium t-butoxide led to the formation of the C-bound cyanomethylene ligand at the metal center. Unlike most previously characterized Ni(II) cyanoalkyls, the resulting complex exhibited quick transformation under aerobic conditions at room temperature to afford CNC-ligated nickel(II) cyanide, indicating facile cleavage of the C–CN bond. The cyanoalkyl and cyanide complexes were isolated in excellent yields and characterized by NMR spectroscopy and single-crystal X-ray diffraction. Carbon-containing products of the aerobic C–CN bond activation are hydroxyacetonitrile, formaldehyde, cyanomethyl formate, and carbon dioxide.more » « lessFree, publicly-accessible full text available July 12, 2024
-
Dutra, Matthew ; Amaya, Jose A. ; McElhenney, Shannon ; Manley, Olivia M. ; Makris, Thomas M. ; Rassolov, Vitaly ; Garashchuk, Sophya ( , The Journal of Physical Chemistry B)
-
Zhang, Libo ; Manley, Olivia M. ; Ma, Dumei ; Yin, Yingwu ; Makris, Thomas M. ; Wang, Qian ( , Bioresource Technology)