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  1. Free, publicly-accessible full text available May 1, 2024
  2. Serverless computing, or Function-as-a-Service (FaaS), enables a new way of building and scaling applications by allowing users to deploy fine-grained functions while providing fully-managed resource provisioning and auto-scaling. Custom FaaS container support is gaining traction as it enables better control over OSes, versioning, and tooling for modernizing FaaS applications. However, providing rapid container provisioning introduces non-trivial challenges for FaaS providers, since container provisioning is costly, and real-world FaaS workloads exhibit highly dynamic patterns. In this paper, we design FaaSNet, a highly-scalable middleware system for accelerating FaaS container provisioning. FaaSNet is driven by the workload and infrastructure requirements of the FaaS platform at one of the world's largest cloud providers, Alibaba Cloud Function Compute. FaaSNet enables scalable container provisioning via a lightweight, adaptive function tree (FT) structure. FaaSNet uses an I/O efficient, on-demand fetching mechanism to further reduce provisioning costs at scale. We implement and integrate FaaSNet in Alibaba Cloud Function Compute. Evaluation results show that FaaSNet: (1) finishes provisioning 2,500 function containers on 1,000 virtual machines in 8.3 seconds, (2) scales 13.4× and 16.3× faster than Alibaba Cloud's current FaaS platform and a state-of-the-art P2P container registry (Kraken), respectively, and (3) sustains a bursty workload using 75.2% less time than an optimized baseline. 
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  4. We report a method to control the composition and microstructure of CdSe 1−x S x nanocrystals by the simultaneous injection of sulfide and selenide precursors into a solution of cadmium oleate and oleic acid at 240 °C. Pairs of substituted thio- and selenoureas were selected from a library of compounds with conversion reaction reactivity exponents ( k E ) spanning 1.3 × 10 −5 s −1 to 2.0 × 10 −1 s −1 . Depending on the relative reactivity ( k Se / k S ), core/shell and alloyed architectures were obtained. Growth of a thick outer CdS shell using a syringe pump method provides gram quantities of brightly photoluminescent quantum dots (PLQY = 67 to 90%) in a single reaction vessel. Kinetics simulations predict that relative precursor reactivity ratios of less than 10 result in alloyed compositions, while larger reactivity differences lead to abrupt interfaces. CdSe 1−x S x alloys ( k Se / k S = 2.4) display two longitudinal optical phonon modes with composition dependent frequencies characteristic of the alloy microstructure. When one precursor is more reactive than the other, its conversion reactivity and mole fraction control the number of nuclei, the final nanocrystal size at full conversion, and the elemental composition. The utility of controlled reactivity for adjusting alloy microstructure is discussed. 
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