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Liu, Jiangsi; Luo, Genming; Lu, Zunli; Lu, Wanyi; Qie, Wenkun; Zhang, Feifei; Wang, Xiangdong; Xie, Shucheng (, Geochemistry, Geophysics, Geosystems)
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He, Ruliang; Lu, Wanyi; Junium, Christopher K.; Ver Straeten, Charles A.; Lu, Zunli (, Geochimica et Cosmochimica Acta)
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Lu, Wanyi; Dickson, Alexander J.; Thomas, Ellen; Rickaby, Rosalind E.M.; Chapman, Piers; Lu, Zunli (, Geochimica et Cosmochimica Acta)
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Lu, Wanyi; Ridgwell, Andy; Thomas, Ellen; Hardisty, Dalton S.; Luo, Genming; Algeo, Thomas J.; Saltzman, Matthew R.; Gill, Benjamin C.; Shen, Yanan; Ling, Hong-Fei; et al (, Science)Rising oceanic and atmospheric oxygen levels through time have been crucial to enhanced habitability of surface Earth environments. Few redox proxies can track secular variations in dissolved oxygen concentrations ([O2]) around threshold levels for metazoan survival in the upper ocean. We present an extensive compilation of iodine to calcium ratios (I/Ca) in marine carbonates. Our record supports a major rise in atmospheric pO2 at ~400 million years ago (Ma), and reveals a step-change in the oxygenation of the upper ocean to relatively sustainable near-modern conditions at ~200 Ma. An Earth system model demonstrates that a shift in organic matter remineralization to greater depths, which may have been due to increasing size and biomineralization of eukaryotic plankton, likely drove the I/Ca signals at ~200 Mamore » « less
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