skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Explore Research Products in the PAR
It may take a few hours for recently added research products to appear in PAR search results.


  • Home
  • Search Results
  • Page 1 of 1

Search for: All records

Award ID contains: 1362118

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. ; ; ; (, Chem. Commun.)
    Targeted as an example of a compound composed of a carbon atom together with two stable neutral leaving groups, 7-isocyano-7-azadibenzonorbornadiene, CN 2 A ( 1 , A = C 14 H 10 or anthracene) has been synthesized and spectroscopically and structurally characterized. The terminal C atom of 1 can be transferred: mesityl nitrile oxide reacts with 1 to produce carbon monoxide, likely via intermediacy of the N -isocyanate OCN 2 A . Reaction of 1 with [RuCl 2 (CO)(PCy 3 ) 2 ] leads to [RuCl 2 (CO)( 1 )(PCy 3 ) 2 ] which decomposes unselectively: in the product mixture, the carbide complex [RuCl 2 (C)(PCy 3 ) 2 ] was detected. Upon heating in the solid state or in solution, 1 decomposes to A , N 2 and cyanogen (C 2 N 2 ) as substantiated using molecular beam mass spectrometry, IR and NMR spectroscopy techniques. 
    more » « less
    Full Text Available