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Abstract The mechanisms controlling transport and retention of microplastics (MPs) in riverine systems are not understood well. We investigated the impact of large roughness elements (LREs) on in-stream transport and retention of the ubiquitous polystyrene-microplastics (PS-MPs). Scaled experiments were conducted with and without LREs under various shear Reynolds numbers (Re*) in an ecohydraulics flume. Our results, for the first time, demonstrated a clear dependence of the MPs’ velocity onRe*in LREs-dominated channel. Two distinct regimes and thresholds were identified: lowerRe*(≤ 15,000) regime corresponding to higher velocities of MPs ($${U}_{MPs}^{*}$$ $U_{\mathrm{MPs}}^{\ast }$> 0.45), and higherRe*(> 15,000) to lower$${U}_{MPs}^{*} ($$ $U_{\mathrm{MPs}}^{\ast }($< 0.45). The presence and higher density of LREs increasedRe*, decreased$${U}_{MPs}^{*}$$ $U_{\mathrm{MPs}}^{\ast }$, and enhanced the PS-MPs capture. The LREs-generated turbulence kinetic energy (TKE) was found to be a good predictor of PS-MPs transport and retention rates, indicating the effectiveness of LREs in retaining PS-MPs in streams and rivers. 

Abstract Dissolved oxygen (DO) indicates the overall stream water quality and ecosystem health. We investigated emergent scaling of DO with the dominant environmental drivers in freshwater (non‐coastal) streams across the contiguous United States. Available data of monthly to quarterly sampling frequencies during 1998–2015 were obtained for 86 U.S. streams. Data analytics indicated water temperature (T_w) and pH (a proxy of carbon dioxide) dominating the key environmental process components of DO concentrations in the freshwater streams. The “climatic” process component (comprising T_wand net radiation) had, respectively, ∼3 and ∼9 times stronger control on DO than the “biogeochemical” (total nitrogen, total phosphorus, pH, and specific conductivity) and “hydro‐atmospheric” exchange (stream flow and atmospheric pressure) components. The predominant climatic control on stream DO was linked to the high extent of vegetated land (on average ∼53%) and steep slope (∼10%) in the draining watersheds, despite the notable presence of agricultural land (∼35%). An emergent power law scaling relationship was then developed to acceptably predict DO (mg/l) based on T_w(K) and pH, with the approximate exponents of −15/2 and 1/2, respectively (Nash‐Sutcliffe Efficiency = 0.72–0.73). The scaling law demonstrated the underlying organizing principles such as the depletion of stream DO due to reduced dissolution and increased metabolic respiration with the increasing temperature and nutrients. The scaling law was persistent across the various U.S. streams, representing gradients in climate, hydrology, biogeochemistry, and land use/cover. The findings would help understand and manage water quality and ecosystem health in freshwater streams across the United States and beyond. 

Abstract The capacity for coastal river networks to transport and transform dissolved organic matter (DOM) is widely accepted. However, climate‐induced shifts in stormwater runoff and tidal extension alter fresh and marine water source contributions, associated DOM, and processing rates of nutrients entering coastal canals. We investigate how time‐variable interactions among coastal water source contributions influence the concentrations of dissolved organic carbon (DOC), nutrients, and DOM composition in urban canals. We quantified the spatiotemporal variability of DOM quality and nutrient concentrations to determine contributions of tidal marine water, rainwater, stormwater runoff, and groundwater to three coastal urban canals of Miami, Florida (USA). We created a Bayesian Monte Carlo mixing model using measurements of fluorescent DOM (fDOM), DOC concentrations, δ¹⁸O and δ²H isotopic signatures, and chloride (Cl⁻). Fractional contributions of groundwater averaged 17% in the dry season and 26% at peak high tide during the subtropical wet season (September–November). The canal‐to‐marine head difference (CMHD) was a primary driver of groundwater contributions to coastal urban canals and monthly patterns of fDOM/DOC. High tide (>1 m) and discharge events were found to connect canals to upstream sources of terrestrial DOM. Loading of terrestrially sourced DOC and DOM is pulsed to urban canals, shunted downstream and supplemented by microbially sourced DOM during the wet season at high tide. Overall, we demonstrate that a combined tracer approach with isotopes and fDOM can help identify groundwater contributions to coastal waterways and that autochthonous fDOM may prime the degradation of carbon or nutrients as the CMHD pushes inland.