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Bheemireddy, Sambasiva R.; Hussain, Waseem A.; Uddin, Ain; Du, Yachu; Hautzinger, Matthew P.; Kevorkian, Paul V.; Petrie, Frankie A.; Plunkett, Kyle N. (, Chemical Communications)Isomerically pure 5,11-dibromo-2,8-dihexylanthra[2,3- b :76- b ′]dithiophene, a brominated analog of anthracenedithiophene (ADT), was prepared and utilized for a palladium catalyzed cyclopentannulation reaction with 3,3′-dimethoxy-phenylacetylene to give cyclopentannulated ADT (CP-ADTs). A further Scholl cyclodehydrogenation reaction gave contorted aromatics with large splay angles, low optical gaps, and low LUMOs.more » « less
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Yu, Jierui; Park, JaeHong; Van Wyk, Andrea; Rumbles, Garry; Deria, Pravas (, Journal of the American Chemical Society)
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Yu, Jierui; Wyk, Andrea Van; Smith, Tanner; Deria, Pravas (, ECS Transactions)
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Van Wyk, Andrea; Smith, Tanner; Park, Jaehong; Deria, Pravas (, Journal of the American Chemical Society)
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