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  1. Sanders, Glen A. ; Lieberman, Robert A. ; Udd Scheel, Ingrid (Ed.)
    Each year, the global cost that is accounted to corrosion was estimated at $2.5 trillion. Corrosion not only imposes an economic burden, when corroded structures are under various loading conditions, it may also lead to structurally brittle failure, posing a potential threat to structural reliability and service safety. Although considerable studies investigated the combined effect of external loads and structural steel corrosion, many of the current findings on synergetic interaction between stress and corrosion are contrary. In this study, the combined effects of dynamic mechanical loads and corrosion on epoxy coated steel are investigated using the distributed fiber optic sensors based on optical frequency domain reflectometry. Experimental studies were performed using the serpentine-arranged distributed fiber optic strain sensors embedded inside the epoxy with three different scenarios including the impact loading-only, corrosion-only, and combined impact loading-corrosion tests. Test results demonstrated that the distributed fiber optic sensors can locate and detect the corrosion processing paths by measuring the induced strain changes. The combined impact loading-corrosion condition showed significantly accelerated corrosion progression caused by mechanical loads, indicating the significant interaction between dynamic mechanical loading and corrosion on epoxy coated steel. 
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    Free, publicly-accessible full text available June 13, 2024
  2. Free, publicly-accessible full text available May 1, 2024
  3. This paper examines the impact of fire on the microstructural, mechanical, and corrosion behavior of wire-arc-sprayed zinc, aluminum, and Zn-Al pseudo-alloy coatings. Steel plates coated with these materials were subjected to temperatures in increments of 100 °C, starting from 300 °C and progressing until failure. Microstructural characterization, microhardness, abrasion resistance, and electrochemical impedance studies were performed on the post-fire coatings. The findings from this study show that heat had a positive impact on the performance of zinc and Zn-Al pseudo-alloy coatings when they were exposed to temperatures of up to 400 °C, while aluminum coatings maintain their performance up to 600 °C. However, above these temperatures, the effectiveness of coatings was observed to decline, due to increased high-temperature oxidation, and porosity, in addition to decreased microhardness, abrasion resistance, and corrosion protection performance. Based on the findings from this study, appropriately sealed thermal-spray-coated steel components can be reused after exposure to fire up to a specific temperature depending on the coating material. 
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    Free, publicly-accessible full text available May 1, 2024
  4. This study presents an experimental investigation on the combined effect of mechanical loads and corrosion using the designed polytetrafluoroethylene tube-packaged fiber Bragg grating (FBG) sensors, as to implement long-gauge FBG (LFBG) sensors in corrosion detection practices for structural health monitoring. A simplified LFBG-based sensing model was proposed for strain measurement in terms of the Bragg wavelength change. Correspondingly, a systematic corrosion assessment strategy was developed to estimate corrosion severity and average corrosion rate. Upon this, the experimental study was performed on epoxy-coated steel specimens embedded with LFBG sensors, where the loading, corrosion, and combined loading–corrosion tests were used to explore the effect of mechanical loads on corrosion behavior. Test results revealed that the specimens subjected to combined conditions exhibited more severe corrosion damage. The maximum mass loss was observed to be 1.82 and 2.43 in percentage under individual corrosion and combined loading–corrosion conditions, respectively. Also, the pit depth under combined conditions was found to develop rapidly in the early stage. The pit depth severity ratio was around 0.2–0.8 during the 67 days of exposure, indicating an evident impact of loading on corrosion severity. Furthermore, the maximum average corrosion rate under combined conditions was found to be 5.66 times that under individual corrosion conditions.

     
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  5. In order to achieve effective monitoring of concrete structures for sound structural health, the addition of carbon nanotubes (CNTs) into cementitious materials offers a promising solution for fabricating CNT-modified smart concrete with self-sensing ability. This study investigated the influences of CNT dispersion method, water/cement (W/C) ratio, and concrete constituents on the piezoelectric properties of CNT-modified cementitious materials. Three CNT dispersion methods (direct mixing, sodium dodecyl benzenesulfonate (NaDDBS) and carboxymethyl cellulose (CMC) surface treatment), three W/C ratios (0.4, 0.5, and 0.6), and three concrete constituent compositions (pure cement, cement/sand, and cement/sand/coarse aggregate) were considered. The experimental results showed that CNT-modified cementitious materials with CMC surface treatment had valid and consistent piezoelectric responses to external loading. The piezoelectric sensitivity improved significantly with increased W/C ratio and reduced progressively with the addition of sand and coarse aggregates. 
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  6. Carbon nanotube (CNT)/epoxy nanocomposites have a great potential of possessing many advanced properties. However, the homogenization of CNT dispersion is still a great challenge in the research field of nanocomposites. This study applied a novel dispersion agent, carboxymethyl cellulose (CMC), to functionalize CNTs and improve CNT dispersion in epoxy. The effectiveness of the CMC functionalization was compared with mechanical mixing and a commonly used surfactant, sodium dodecylbenzene sulfonate (NaDDBS), regarding dispersion, mechanical and corrosion properties of CNT/epoxy nanocomposites with three different CNT concentrations (0.1%, 0.3% and 0.5%). The experimental results of Raman spectroscopy, particle size analysis and transmission electron microscopy showed that CMC functionalized CNTs reduced CNT cluster sizes more efficiently than NaDDBS functionalized and mechanically mixed CNTs, indicating a better CNT dispersion. The peak particle size of CMC functionalized CNTs reduced as much as 54% (0.1% CNT concentration) and 16% (0.3% CNT concentration), compared to mechanical mixed and NaDDBS functionalized CNTs. Because of the better dispersion, it was found by compressive tests that CNT/epoxy nanocomposites with CMC functionalization resulted in 189% and 66% higher compressive strength, 224% and 50% higher modulus of elasticity than those with mechanical mixing and NaDDBS functionalization respectively (0.1% CNT cencentration). In addition, electrochemical corrosion tests also showed that CNT/epoxy nanocomposites with CMC functionalization achieved lowest corrosion rate (0.214 mpy), the highest corrosion resistance (201.031 Ω·cm2), and the lowest porosity density (0.011%). 
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  7. Fiber Bragg grating (FBG) sensors have been applied to assess strains, stresses, loads, corrosion, and temperature for structural health monitoring (SHM) of steel infrastructure, such as buildings, bridges, and pipelines. Since a single FBG sensor measures a particular parameter at a local spot, it is challenging to detect different types of anomalies and interactions of anomalies. This paper presents an approach to assess interactive anomalies caused by mechanical loading and corrosion on epoxy coated steel substrates using FBG sensors in real time. Experiments were performed by comparing the monitored center wavelength changes in the conditions with loading only, corrosion only, and simultaneous loading and corrosion. The theoretical and experimental results indicated that there were significant interactive influences between loading and corrosion for steel substrates. Loading accelerated the progress of corrosion for the epoxy coated steel substrate, especially when delamination in the epoxy coating was noticed. Through the real-time monitoring from the FBG sensors, the interactions between the anomalies induced by the loading and corrosion can be quantitatively evaluated through the corrosion depth and the loading contact length. These fundamental understandings of the interactions of different anomalies on steel structures can provide valuable information to engineers for better management of steel structures. 
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