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Flexible direct synthesis of phosphorus-rich CoP ₃ on carbon black and its examination in hydrogen evolution electrocatalysis

https://doi.org/10.1039/D3YA00295K

Liyanage, Ishanka A.; Barmore, Hannah; Gillan, Edward G. (September 2023, Energy Advances)

The reaction of CoCl₂ on carbon black with phosphorus yields crystalline CoP₃ particles on a carbon. Low CoP₃ (5–25 mol%) content is distributed on the carbon support and shows electrocatalytic hydrogen evolution activity similar to bulk CoP₃.
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Rapid and Energetic Solid-State Metathesis Reactions for Iron, Cobalt, and Nickel Boride Formation and Their Investigation as Bifunctional Water Splitting Electrocatalysts

https://doi.org/10.1021/acsmaterialsau.1c00079

Abeysinghe, Janaka P.; Kölln, Anna F.; Gillan, Edward G. (April 2022, ACS Materials Au)
Gold Nanostar Spatial Distribution Impacts the Surface-Enhanced Raman Scattering Detection of Uranyl on Amidoximated Polymers

https://doi.org/10.1021/acs.langmuir.1c00132

Phan, Hoa T.; Vinson, Claire; Haes, Amanda J. (April 2021, Langmuir)

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Mechanical rigidity of a shape-memory metal–organic framework increases by crystal downsizing

https://doi.org/10.1039/D0CC05684G

Tiba, Al A.; Conway, Matthew T.; Hill, Collin S.; Swenson, Dale C.; MacGillivray, Leonard R.; Tivanski, Alexei V. (January 2021, Chemical Communications)

Soft porous nanocrystals with a pronounced shape-memory effect exhibit two- to three-fold increase in elastic modulus compared to the microcrystalline counterpart as determined by atomic force microscopy nanoindentation. The increase in rigidity is consistent with the known shape-memory effect displayed by the framework solid at the nanoscale. Crystal downsizing can offer new avenues for tailoring the mechanical properties of metal–organic frameworks.
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