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Abstract We propose a new scalable platform for quantum computing (QC)—an array of optically trapped symmetric-top molecules (STMs) of the alkaline earth monomethoxide (MOCH₃) family. Individual STMs form qubits, and the system is readily scalable to 100–1000 qubits. STM qubits have desirable features for QC compared to atoms and diatomic molecules. The additional rotational degree of freedom about the symmetric-top axis gives rise to closely spaced opposite parityK-doublets that allow full alignment at low electric fields, and the hyperfine structure naturally provides magnetically insensitive states with switchable electric dipole moments. These features lead to much reduced requirements for electric field control, provide minimal sensitivity to environmental perturbations, and allow for 2-qubit interactions that can be switched on at will. We examine in detail the internal structure of STMs relevant to our proposed platform, taking into account the full effective molecular Hamiltonian including hyperfine interactions, and identify useable STM qubit states. We then examine the effects of the electric dipolar interaction in STMs, which not only guide the design of high-fidelity gates, but also elucidate the nature of dipolar exchange in STMs. Under realistic experimental parameters, we estimate that the proposed QC platform could yield gate errors at the 10⁻³level, approaching that required for fault-tolerant QC. 

Ultracold polyatomic molecules have potentially wide-ranging applications in quantum simulation and computation, particle physics, and quantum chemistry. For atoms and small molecules, direct laser cooling has proven to be a powerful tool for quantum science in the ultracold regime. However, the feasibility of laser-cooling larger, nonlinear polyatomic molecules has remained unknown because of their complex structure. We laser-cooled the symmetric top molecule calcium monomethoxide (CaOCH₃), reducing the temperature of ~10⁴molecules from 22 ± 1 millikelvin to 1.8 ± 0.7 millikelvin in one dimension and state-selectively cooling two nuclear spin isomers. These results demonstrate that the use of proper ro-vibronic transitions enables laser cooling of nonlinear molecules, thereby opening a path to efficient cooling of chiral molecules and, eventually, optical tweezer arrays of complex polyatomic species.