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Abstract BackgroundTwo major factors that determine the efficiency of programs designed to mitigate greenhouse gases by encouraging voluntary changes in U.S. agricultural land management are the effect of land use changes on producers’ profitability and the net sequestration those changes create. In this work, we investigate how the interaction of these factors produces spatial heterogeneity in the cost-efficiency of voluntary programs incentivizing tillage reduction and cover-cropping practices. We map county-level predicted rates of adoption for each practice with the greenhouse gas mitigation or carbon sequestration benefits expected from their use. Then, we use these bivariate maps to describe how the cost efficiency of agricultural mitigation efforts is likely to vary spatially in the United States. ResultsOur results suggest the combination of high adoption rates and large reductions in net emissions make reduced tillage programs most cost efficient in the Chesapeake Bay watershed or the Upper Mississippi and Lower Missouri sub-basins of the Mississippi River. For programs aiming to reduce net emissions by incentivizing cover-cropping, we expect cost-efficiency to be greatest in the areas near the main stem of the Mississippi River within its Middle and Lower sections. ConclusionsMany voluntary agricultural conservation programs offer the same incentives across the United States. Yet spatial variation in profitability and efficacy of conservation practices suggest that these uniform approaches are not cost-effective. Spatial targeting of voluntary agricultural conservation programs has the potential to increase the cost-efficiency of these programs due to regional heterogeneity in the profitability and greenhouse gas mitigation benefits of agricultural land management practices across the continental United States. We illustrate how predicted rates of adoption and greenhouse gas sequestration might be used to target regions where efforts to incentivize cover-cropping and reductions in tillage are most likely to be cost -effective. 

Abstract An experimental apparatus was designed to study the impacts of wettability on evaporation of water from Ottawa sand. Evaporation rates were measured for: (1) a 5.7-cm-thick layer of hydrophilic Ottawa sand; (2) a 5.7-cm-thick layer with 12% hydrophobic content, consisting of a 0.7-cm-layer of n-Octyltriethoxysilane-coated hydrophobic sand buried 1.8 cm below the surface of hydrophilic sand; and (3) a 5.7-cm-thick layer with mixed wettabilities, consisting of 12% n-Octyltriethoxysilane-coated hydrophobic sand mixed into hydrophilic sand. The sand–water mixtures experienced forced convection above and through the sand layer, while a simulated solar flux (i.e., 112±20 W/m2) was applied. Evaporation from homogeneous porous media is classified into the constant-rate, falling-rate, and slow-rate periods. Wettability affected the observed evaporation mechanisms, including the transition from constant-rate to falling-rate periods. Evaporation entered the falling-rate period at 12%, 20%, and 24% saturations for the all hydrophilic sand, hydrophobic layer, and hydrophobic mixture, respectively. Wettability affected the duration of the experiments, as the all hydrophilic sand, hydrophobic layer, and hydrophobic mixture lasted 17, 20, and 26 trials, respectively. Both experiments with hydrophobic particles lasted longer than the all hydrophilic experiment and had shorter constant-rate evaporation periods, suggesting hydrophobic material interrupts capillary action of water to the soil surface and reduces evaporation. Sand temperatures suggest more evaporation occurred near the test section inlet for higher saturations and the hydrophobic layer experienced more evaporation occur near the outlet. Evaporation fluxes were up to 12× higher than the vapor diffusion flux due to enhanced vapor diffusion and forced convection. 

Abstract Drying front propagation and coupled heat and mass transfer analysis from porous media is critical for soil–water dynamics, electronics cooling, and evaporative drying. In this study, de-ionized water was evaporated from three 3D printed porous structures (with 0.41 mm, 0.41 mm, and 0.16 mm effective radii, respectively) created out of acrylonitrile butadiene styrene (ABS) plastic using stereolithography technology. The structures were immersed in water until all the pores were invaded and then placed on the top of a sensitive scale to record evaporative mass loss. A 1000 W/m2 heat flux was applied with a solar simulator to the top of each structure to accelerate evaporation. The evaporative mass losses were recorded at 15 min time intervals and plotted against time to compare evaporation rates from the three structures. The evaporation phenomena were captured with a high-speed camera from the side of the structures to observe the drying front propagation during evaporation, and a high-resolution thermal camera was used to capture images to visualize the thermal gradients during evaporation. The 3D-structure with the smallest effective pore radius (i.e., 0.16 mm) experienced the sharpest decrease in the mass loss as the water evaporated from 0.8 g to 0.1 g within 180 min. The designed pore structures influenced hydraulic linkages, and therefore, evaporation processes. A coupled heat-and-mass-transfer model modeled constant rate evaporation, and the falling rate period was modeled through the normalized evaporation rate. 

The Ogallala Aquifer, a primary irrigation water source in the High Plains region of the United States, is declining, thereby necessitating new water conservation strategies. This paper investigates the impact of mixed wettability on the evaporation dynamics of a 10-µl sessile water droplet placed within simulated soil pores comprised of hydrophobic Teflon beads (CA ∼ 108°) and hydrophilic glass (CA ∼ 41°) beads with 2.38-mm diameters, where homogeneous and heterogenous (i.e., mixed hydrophobicity and hydrophilicity) wettability configurations were investigated. Experiments were performed in an environmental chamber where the relative humidity and temperature were 60% ± 0.1% RH and 20 ± 0.4 °C, respectively. Wettability influenced evaporation times, with homogeneous hydrophobic pores (i.e., three Teflon beads) and heterogenous one glass, two Teflon pores having the longest average evaporation times of 40 and 39 min, respectively. Homogeneous hydrophilic pores (i.e., three glass beads) and heterogenous two glass, one Teflon pores exhibited evaporation times of 34 min. Evaporation times for heterogenous combinations trended based on the predominant wettability. Contact angles and the projected length of contact were analyzed from videos to capture pinning and depinning during evaporation. For many cases including hydrophobicity, contact angles were less than 90°, and in some configurations, water would be pinned on a Teflon bead, whereas depinning (i.e., moving) on a glass bead. Stick-slip evaporation was observed, where the evaporating droplet switched between constant contact radius and constant contact area evaporative modes to minimize droplet surface energy. The results suggest wettability alterations in agricultural settings may reduce evaporation.