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Open questions about the modulation of near‐surface trace gas variability by stratosphere‐troposphere tracer transport complicate efforts to identify anthropogenic sources of gases such as CFC‐11 and N₂O and disentangle them from dynamical influences. In this study, we explore one model's modulation of lower stratospheric tracer advection by the quasi‐biennial oscillation (QBO) of stratospheric equatorial zonal‐mean zonal winds at 50 hPa. We assess instances of coherent modulation versus disruption through phase unlocking with the seasonal cycle in the model and in observations. We quantify modeled advective contributions to the temporal rate of change of stratospheric CFC‐11 and N₂O at extratropical and high‐latitudes by calculating a transformed Eulerian mean (TEM) budget across isentropic surfaces from a 10‐member WACCM4 ensemble simulation. We find that positive interannual variability in seasonal tracer advection generally occurs in the easterly QBO phase, as in previous work, and briefly discuss physical mechanisms. Individual simulations of the 10‐member ensemble display phase‐unlocking disruptions from this general pattern due to seasonally varying synchronizations between the model's repeating 28‐month QBO cycle and the 12‐month seasonal cycle. We find that phase locking and unlocking patterns of tracer advection calculations inferred from observations fall within the envelope of the ensemble member results. Our study bolsters evidence for variability in the interannual stratospheric dynamical influence of CFC‐11 near‐surface concentrations by assessing the QBO modulation of lower stratospheric advection via synchronization with the annual cycle. It identifies a likely cause of variations in the QBO influence on tropospheric abundances.

 

The inorganic chlorine (Cl_y) and odd nitrogen (NO_y) chemical families influence stratospheric O₃. In January 2020 Australian wildfires injected record‐breaking amounts of smoke into the southern stratosphere. Within 1–2 months ground‐based and satellite observations showed Cl_yand NO_ywere repartitioned. By May, lower stratospheric HCl columns declined by ∼30% and ClONO₂columns increased by 40%–50%. The Cl_yperturbations began and ended near the equinoxes, increased poleward, and peaked at the winter solstice. NO₂decreased from February to April, consistent with sulfate aerosol reactions, but returned to typical values by June ‐ months before the Cl_yrecovery. Transport tracers show that dynamics not chemistry explains most of the observed O₃decrease after April, with no significant transport earlier. Simulations assuming wildfire smoke behaves identically to sulfate aerosols couldn't reproduce observed Cl_ychanges, suggesting they have different composition and chemistry. This undermines our ability to predict ozone in a changing climate.

 

As the leading mode of Pacific variability, El Niño–Southern Oscillation (ENSO) causes vast and widespread climatic impacts, including in the stratosphere. Following discovery of a stratospheric pathway of ENSO to the Northern Hemisphere surface, here we aim to investigate if there is a substantial Southern Hemisphere (SH) stratospheric pathway in relation to austral winter ENSO events. Large stratospheric anomalies connected to ENSO occur on average at high SH latitudes as early as August, peaking at around 10 hPa. An overall colder austral spring Antarctic stratosphere is generally associated with the warm phase of the ENSO cycle, and vice versa. This behavior is robust among reanalysis and six separate model ensembles encompassing two different model frameworks. A stratospheric pathway is identified by separating ENSO events that exhibit a stratospheric anomaly from those that do not and comparing to stratospheric extremes that occur during neutral ENSO years. The tropospheric eddy-driven jet response to the stratospheric ENSO pathway is the most robust in the spring following a La Niña, but extends into summer, and is more zonally symmetric compared to the tropospheric ENSO teleconnection. The magnitude of the stratospheric pathway is weaker compared to the tropospheric pathway and therefore, when it is present, has a secondary role. For context, the magnitude is approximately half that of the eddy-driven jet modulation due to austral spring ozone depletion in the model simulations. This work establishes that the stratospheric circulation acts as an intermediary in coupling ENSO variability to variations in the austral spring and summer tropospheric circulation.

 

The 2015 and 2020 ozone holes set record sizes in October–December. We show that these years, as well as other recent large ozone holes, still adhere to a fundamental recovery metric: the later onset of early spring ozone depletion as chlorine and bromine diminishes. This behavior is also captured in the Whole Atmosphere Chemistry Climate Model. We quantify observed recovery trends of the onset of the ozone hole and in the size of the September ozone hole, with good model agreement. A substantial reduction in ozone hole depth during September over the past decade is also seen. Our results indicate that, due to dynamical phenomena, it is likely that large ozone holes will continue to occur intermittently in October–December, but ozone recovery will still be detectable through the later onset, smaller, and less deep September ozone holes: metrics that are governed more by chemical processes.

 

The expansion of Antarctic sea ice since 1979 in the presence of increasing greenhouse gases remains one of the most puzzling features of current climate change. Some studies have proposed that the formation of the ozone hole, via the Southern Annular Mode, might explain that expansion, and a recent paper highlighted a robust causal link between summertime Southern Annular Mode (SAM) anomalies and sea ice anomalies in the subsequent autumn. Here we show that many models are able to capture this relationship between the SAM and sea ice, but also emphasize that the SAM only explains a small fraction of the year‐to‐year variability. Finally, examining multidecadal trends, in models and in observations, we confirm the findings of several previous studies and conclude that the SAM–and thus the ozone hole–are not the primary drivers of the sea ice expansion around Antarctica in recent decades.

 

The forecast potential of springtime ozone on April surface temperatures at particular locations in the Northern Hemisphere has been previously reported. Evidence suggests that early springtime Arctic stratospheric ozone acts as a proxy for extreme events in the winter polar vortex. Here, using a state‐of‐the‐art chemistry‐climate model, reanalysis and observations, we extend the forecast potential of ozone on surface temperatures to aspects of the Northern Hemisphere cryosphere. Sea ice fraction and sea ice extent differences between years of March high and low Arctic stratospheric ozone extremes show excellent agreement between an ensemble of chemistry‐climate model simulations and observations, with differences occurring not just in April but extending through to the following winter season in some locations. Large snow depth differences are also obtained in regional locations in Russia and along the southeast coast of Alaska. These differences remain elevated until early summer, when snow cover diminishes. Using a conditional empirical model in a leave‐three‐out cross validation method, March total column ozone is able to accurately predict the sign of the observed sea ice extent and snow depth anomalies over 70% of the time during an ozone extreme year, especially in the region of the Bering strait and the Greenland Sea, which could be useful for shipping routes and for testing climate models.

 

Using the Whole Atmosphere Community Climate Model version 6, stratospheric ozone in the Last Glacial Maximum (LGM) is investigated. It is shown that, compared with preindustrial (PI) times, LGM modeled stratospheric temperatures are increased by up to 8 K, leading to faster ozone destruction rates for gas phase reactions, especially via the Chapman mechanism. On the other hand, stratospheric hydroxyl radical (OH) and nitrogen oxides (NO_x) concentrations are decreased by 10–20%, which decreases catalytic ozone destruction, thereby decreasing ozone loss rates. The net effect of these two compensating mechanisms in the upper stratosphere (above 15 hPa) is a vertically integrated 1–3 Dobson unit (DU) decrease during the LGM. In the lower stratosphere (tropopause to 15 hPa), changes in the stratospheric overturning circulation and resulting transport dominate changes in ozone. Consistent with a weakening of the residual circulation in the LGM, lower stratospheric ozone is increased by 2–5 DU in the tropics and decreased by 5–10 DU in the extratropics, but the latter is partly compensated by ozone increases due to a lower tropopause. It is found that tropospheric ozone is decreased by about 5 DU in the LGM versus PI. Combined changes in stratospheric and tropospheric ozone lead to a decrease in total ozone column everywhere except over the northeast North America, equatorial Indian and West Pacific Oceans. Surface ultraviolet radiation in the LGM versus PI is increased over the Northern Hemisphere middle and high latitudes, especially over the ice caps, and over the Southern Hemisphere near 60°S.

 

Quantifying the width of the tropics has important implications for understanding climate variability and the atmospheric response to anthropogenic forcing. Considerable effort has been placed on quantifying the width of the tropics at tropospheric levels, but substantially less effort has been placed on quantifying the width at stratospheric levels. Here we probe tropical width in the stratosphere using chemical tracers, which are accessible by direct measurement. Two new tracer‐based width metrics are developed, denoted here as the “1σ method” and the gradient weighted latitude (GWL) method. We evaluate widths from three tracers, CH₄, N₂O, and SF₆. We demonstrate that unlike previously proposed stratospheric width methods using tracers, these metrics perform consistently throughout the depth of the stratosphere, at all times of year and on coarse temporal data. The GWL tracer‐based widths correlate well with the turnaround latitude and the critical level, where wave dissipation occurs, in the upper and midstratosphere during certain months of the year. In the lower stratosphere, the deseasonalized tracer‐based widths near the tropical tropopause correlate with the deseasonalized tropopause‐height based metrics. We also find that tracer‐tracer width correlations are strongest at pressure levels where their chemical lifetimes are similar. These metrics represent another useful way to estimate stratospheric tropical width and explore any changes under anthropogenic forcing.

 

The Brewer‐Dobson circulation during the Last Glacial Maximum (LGM) is investigated in simulations using the Whole Atmosphere Community Climate Model version 6. We examine vertical mass fluxes, age of stratospheric air, and the transformed Eulerian mean stream function and find that the modeled annual‐mean Brewer‐Dobson circulation during the LGM is almost everywhere slower than that in the modern climate (with or without anthropogenic ozone depleting substances). Compared to the modern climate, the annual‐mean tropical upwelling in the LGM is 11.3–16.9%, 11.2–15.8%, and 4.4–10.2% weaker, respectively, at 100, 70, and 30 hPa. Simulated decreases in annual‐mean mass fluxes at 70 and 100 hPa are caused by a weaker parameterized orographic gravity wave drag and resolved wave drag, respectively.

 

In 1967, scientists used a simple climate model to predict that human-caused increases in atmospheric CO 2 should warm Earth’s troposphere and cool the stratosphere. This important signature of anthropogenic climate change has been documented in weather balloon and satellite temperature measurements extending from near-surface to the lower stratosphere. Stratospheric cooling has also been confirmed in the mid to upper stratosphere, a layer extending from roughly 25 to 50 km above the Earth’s surface (S 25 − 50 ). To date, however, S 25 − 50 temperatures have not been used in pattern-based attribution studies of anthropogenic climate change. Here, we perform such a “fingerprint” study with satellite-derived patterns of temperature change that extend from the lower troposphere to the upper stratosphere. Including S 25 − 50 information increases signal-to-noise ratios by a factor of five, markedly enhancing fingerprint detectability. Key features of this global-scale human fingerprint include stratospheric cooling and tropospheric warming at all latitudes, with stratospheric cooling amplifying with height. In contrast, the dominant modes of internal variability in S 25 − 50 have smaller-scale temperature changes and lack uniform sign. These pronounced spatial differences between S 25 − 50 signal and noise patterns are accompanied by large cooling of S 25 − 50 (1 to 2 ° C over 1986 to 2022) and low S 25 − 50 noise levels. Our results explain why extending “vertical fingerprinting” to the mid to upper stratosphere yields incontrovertible evidence of human effects on the thermal structure of Earth’s atmosphere.