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Abstract Complete theoretical understanding of the most complex superconductors requires a detailed knowledge of the symmetry of the superconducting energy-gap$${\mathrm{{\Delta}}}_{\mathbf{k}}^\alpha$$ ${\Delta }_k^{\alpha }$, for all momentakon the Fermi surface of every bandα. While there are a variety of techniques for determining$$|{\mathrm{{\Delta}}}_{\mathbf{k}}^\alpha |$$ $\mid {\Delta }_k^{\alpha }\mid$, no general method existed to measure the signed values of$${\mathrm{{\Delta}}}_{\mathbf{k}}^\alpha$$ ${\Delta }_k^{\alpha }$. Recently, however, a technique based on phase-resolved visualization of superconducting quasiparticle interference (QPI) patterns, centered on a single non-magnetic impurity atom, was introduced. In principle, energy-resolved and phase-resolved Fourier analysis of these images identifies wavevectors connecting allk-space regions where$${\mathrm{{\Delta}}}_{\mathbf{k}}^\alpha$$ ${\Delta }_k^{\alpha }$has the same or opposite sign. But use of a single isolated impurity atom, from whose precise location the spatial phase of the scattering interference pattern must be measured, is technically difficult. Here we introduce a generalization of this approach for use with multiple impurity atoms, and demonstrate its validity by comparing the$${\mathrm{{\Delta}}}_{\mathbf{k}}^\alpha$$ ${\Delta }_k^{\alpha }$it generates to the$${\mathrm{{\Delta}}}_{\mathbf{k}}^\alpha$$ ${\Delta }_k^{\alpha }$determined from single-atom scattering in FeSe where s_±energy-gap symmetry is established. Finally, to exemplify utility, we use the multi-atom technique on LiFeAs and find scattering interference between the hole-like and electron-like pockets as predicted for$${\mathrm{{\Delta}}}_{\mathbf{k}}^\alpha$$ ${\Delta }_k^{\alpha }$of opposite sign. 

Josephson scanning tunneling microscopy (JSTM) is a powerful probe of the local superconducting order parameter, but studies have been largely limited to cases where the superconducting sample and superconducting tip both have the same gap symmetry—either s-wave or d-wave. It has been generally assumed that, in an ideal s-to-d JSTM experiment, the critical current would vanish everywhere, as expected for ideal c-axis planar junctions. We show here that this is not the case. Employing first-principlesWannier functions for Bi2Sr2CaCu2O8+δ , we develop a scheme to compute the Josephson critical current (Ic) and quasiparticle tunneling current measured by JSTM with subangstrom resolution. We demonstrate that the critical current for tunneling between an s-wave tip and a superconducting cuprate sample has the largest magnitude above O sites and it vanishes above Cu sites. Ic changes sign under π/2 rotation and its average over a unit cell vanishes, as a direct consequence of the d-wave gap symmetry in cuprates. Further, we show that Ic is strongly suppressed in the close vicinity of a Zn-like impurity owing to suppression of the superconducting order parameter. More interestingly, Ic acquires nonvanishing values above the Cu sites near the impurity. The critical current modulations produced by the impurity occur at characteristic wave vectors distinct from the quasiparticle interference (QPI) analog. Furthermore, the quasiparticle tunneling spectra in the JSTM setup shows coherence peaks and impurity-induced resonances shifted by the s-wave tip gap. We discuss the similarities and differences in JSTM observables and conventional STM observables, making specific predictions that can be tested in future JSTM experiments. 

Abstract Visualizing atomic-orbital degrees of freedom is a frontier challenge in scanned microscopy. Some types of orbital order are virtually imperceptible to normal scattering techniques because they do not reduce the overall crystal lattice symmetry. A good example is d xz / d yz (π,π) orbital order in tetragonal lattices. For enhanced detectability, here we consider the quasiparticle scattering interference (QPI) signature of such (π,π) orbital order in both normal and superconducting phases. The theory reveals that sublattice-specific QPI signatures generated by the orbital order should emerge strongly in the superconducting phase. Sublattice-resolved QPI visualization in superconducting CeCoIn 5 then reveals two orthogonal QPI patterns at lattice-substitutional impurity atoms. We analyze the energy dependence of these two orthogonal QPI patterns and find the intensity peaked near E  = 0, as predicted when such (π,π) orbital order is intertwined with d -wave superconductivity. Sublattice-resolved superconductive QPI techniques thus represent a new approach for study of hidden orbital order. 

Abstract An unidentified quantum fluid designated the pseudogap (PG) phase is produced by electron-density depletion in the CuO 2 antiferromagnetic insulator. Current theories suggest that the PG phase may be a pair density wave (PDW) state characterized by a spatially modulating density of electron pairs. Such a state should exhibit a periodically modulating energy gap $${\Delta }_{{{{{{\rm{P}}}}}}}({{{{{\boldsymbol{r}}}}}})$$ Δ P ( r ) in real-space, and a characteristic quasiparticle scattering interference (QPI) signature $${\Lambda }_{{{{{{\rm{P}}}}}}}({{{{{\boldsymbol{q}}}}}})$$ Λ P ( q ) in wavevector space. By studying strongly underdoped Bi 2 Sr 2 CaDyCu 2 O 8 at hole-density ~0.08 in the superconductive phase, we detect the 8 a 0 -periodic $${\Delta }_{{{{{{\rm{P}}}}}}}({{{{{\boldsymbol{r}}}}}})$$ Δ P ( r ) modulations signifying a PDW coexisting with superconductivity. Then, by visualizing the temperature dependence of this electronic structure from the superconducting into the pseudogap phase, we find the evolution of the scattering interference signature $$\Lambda ({{{{{\boldsymbol{q}}}}}})$$ Λ ( q ) that is predicted specifically for the temperature dependence of an 8 a 0 -periodic PDW. These observations are consistent with theory for the transition from a PDW state coexisting with d -wave superconductivity to a pure PDW state in the Bi 2 Sr 2 CaDyCu 2 O 8 pseudogap phase.